电解法从铅阳极泥提取铋研究.docVIP

PAGE PAGE 8 电解法从铅阳极泥提取铋的研究 陈汉森资助项目：校企合作项目“高铋铅阳极泥综合回收利用试验研究”（No.619320130038）作者简介：陈汉森(1989-)，男，硕士研究生通讯作者：徐瑞东(1975-)，男，教授，博士生导师，E-mail 资助项目：校企合作项目“高铋铅阳极泥综合回收利用试验研究”（No.619320130038） 作者简介：陈汉森(1989-)，男，硕士研究生 通讯作者：徐瑞东(1975-)，男，教授，博士生导师，E-mail：rdxupaper@ (1.昆明理工大学冶金与能源工程学院，云南昆明 650093；2.云南省复杂有色金属资源清洁利用国家重点实验室(培育)，云南昆明 650093；3.云南铜业股份有限公司冶炼加工总厂，昆明 650102) 摘要:从铅阳极泥中提取铋并富集金银等有价金属元素，对提高冶金二次资源的综合利用具有重要意义。本文将脱砷后铅阳极泥熔铸成粗铋作为BiCl3-HCl-NaCl电解体系的阳极，重点研究了温度、电流密度、酸度、Bi3+浓度、NaCl添加量对电解过程的影响。考察了电流效率、电能消耗及阴极产物纯度。结果表明：在电解液温度30℃、电流密度150A/m2、游离HCl浓度80g/L、Bi3+浓度120g/L、NaCl添加量80g/L条件下，得到了致密的薄板状阴极铋，电流效率达到98%，电能消耗约为136kW·h/tBi，阴极铋纯度达到 关键词：脱砷；铅阳极泥；电解；回收 Recovery of Bismuth from Lead Anode Slime by Electrolysis CHEN Hansen1,2, XU Ruidong1,2*，ZHU Yu1,2, HE Shiwei1,2, HUA Hongquan3, Li Yingwei3 (1.Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093; 2.State Key Laboratory Breeding Base of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province, Kunming 650093; 3.Metallurgical Processing Plant, Yunnan Copper Co Ltd, Kunming 650102) Abstract: The extraction of bismuth and enrichment of other valuable metals such as gold and silver elements from lead anode slime that was important to improve the comprehensive utilization of metallurgical secondary resources. In this paper, lead anode slime of arsenic removal was cast into the crude bismuth which as anode on BiCl3-HCl-NaCl electrolyte system. The influences of temperature, current density, acidity, Bi3+ concentration, the addition level of NaCl on the electrolysis process were discussed. The current efficiency, power consumption and purity of cathode product were investigated. Optimum process parameters, namely, temperature of 30℃, current density of 150A/m2, acidity of 80g/L, Bi3+ concentration of 120g/L, the addition level of NaCl of 80g/L, were ascertained. The result show that under optimum conditions, dense sheet-shaped cathode bismuth was obtained, current efficiency