GESTEL2搅拌子吸附萃取法.ppt

Concentration: 25 - 1500 pg/L SBSE - Linearity triphenyl-Sn More than 100 stir bars have been ditributed and all users seem to be excited about the performance Conclusion and Future Developments New Trends Liquid Desorption Gaseous Samples Example Organolead Compounds Solid Samples Enfleurage Technique, Skin, etc. New Medium Polar and Polar Sorbents Selective Sorbents Organo - Pb208 Installed for 1 h on a SBSE - Gaseous Sampling SBSE - Semivolatiles 1 SBSE - Semivolatiles 2 Stir Bar Sorptive Extraction (SBSE) 搅拌子吸附萃取法 朱智华 应用工程师 导言 – 吸附 吸附萃取得历史 搅拌条吸附萃取 SBSE – 理论 SBSE – 原理及仪器 SBSE －质量控制 SBSE －痕量分析 SBSE －超痕量分析 结束 内容 Most commonly applied sorbent: PDMS Best GC stationary phase (apolar) Decomposition products very specific and not related with solutes of interest Retention indices available for a wide number of compounds Water/PDMS distribution ~ Water/Octanol distribution, Ko/w values can be applied 导言－吸附 Available techniques for sorptive enrichment: Open Tubular Trapping (OTT) Solid Phase Microextraction (SPME) Packed PDMS tubes Sensitivity of these techniques is primarily determined by the amount of sorbent employed ! 吸附技术的历史 Based on a trap containing 100 % PDMS particles for analyte trapping similar to solid phase extraction or air adsorption tubes Maximum amount of sorbent: 250 mg -- high sensitivity Dynamic sampling of both aqueous and gaseous samples Quantitative trapping of all analytes: breakthrough sampling Full equilibration of PDMS trap: equilibrium sampling Advantages: Large amount of sorbent, thus high enrichment High maximum flow rates, thus rapid sampling Limitations: Loss of volatiles during drying (aqueous samples) 吸附技术的历史－ PDMS traps Origin: Publication on the SPME extraction of PCBs Authors found very low recoveries for compounds with Ko/w values of up to 1010 Repeating the SPME experiments : Similar SPME recoveries were obtained However, more than 80 % of the spiked analytes were adsorbed on the (Teflon) stir bar Idea: