废轮胎的热解行为_废轮胎的热解行为.pdfVIP

Vol. 31 No. 5 ( ) 2005-10 Journal of E ast China University of Science an T echnology ( Natural Science E ition) 567 : 1006-3080( 2005) 05-0567-04 黄　科, 　高庆华, 　唐黎华, 　倪燕慧, 　朱子彬* ( 华东理工大学化学工艺研究所, 上海200237) : 考察温度、 粒度等热解条件对废轮胎热解行为的影响。采用程序升温热天平仪考察温 度、 粒度对废轮胎热失重的影响; 采用管式反应器考察温度、 粒度对热解产品( 包括热解气、热 解油和粗炭黑) 收率的影响。实验表明: 温度是影响废轮胎热解产品收率的关键因素, 400 ～550 °C 时热解失重速率最快, 超过550 °接近完全热解; 若废轮胎热解以得到热解油为目的, 温度控制在 C 400 ～500 °时, 热解油产率最高。 粒大小也是影响产品收率的重要因素, 在400 ～550 °, 随着 C C 粒度的增加废轮胎热解更加完全, 粒径为0. 3 mm 和5. 0 mm 的废轮胎 粒热解活化能分别为 73. 1 kJ/ mol 和55. 8 kJ/ mol; 粒度对产品收率的影响也很大, 而当 粒度超过5 mm 时对热解产 品的影响较小。 : 废轮胎; 热解; 粒度; 热解动力学 : T Q325 : A Perf ormance of Scrap Tyres Pyrolysis , - , - , - , - * H UA N G K e GA O Qing hua TA N G L i hua N I Yan hui ZH U Zi bin (R esearch Inst itute of Chemic a Techno ogy , E ast Ch ina Univ e rs ity of S cience and Techno ogy , S hang hai 200237, China) Abstract: Effects of the pyrolysis con ition such as temperature an grain size on the performance of scrap tyres w ere stu ie . T hermal gravimetric analyzer w as use to analyze the effect of temperature an grain size on thermogravimetric of scrap tyres. Scrap tyres particles w ere pyrolysise in a tubular reactor to stu y the effect of temperature an grain size on the pro uct yiel s T he results in icate that the effect. of temperature on scrap tyres pyrolysis is critical. Betw een 400 C an 500 C, w eight loss rate was rapi , an scrap tyres pyrolysise completely . T he pyrolytic temperature must be limite between 400 C an 500