催化汽油硫含量分布的数学模拟研究-浙江工业大学学报.pdf

第39 卷第3 期 V ol.39 N o.3 20 11 年6 月 JO U RN A L O F Z H EJ IA NG U N IV ERSIT Y OF T E CHN O LOG Y Jun.2011 　, ( , 310032) :通过对催化汽油的简单蒸馏、硫含量测定,进行了催化汽油硫含量分布的数学模拟 究. 究 结果表明, 催化汽油馏分越重,其硫含量越高,轻催化汽油基本不含硫, 硫主要分布在重汽油中.经 过模型方程推导和参数估值, 建立了硫含量分布数学模型.统计检验结果表明:硫含量模型(n=1) 的模拟计算精度较高, 是较理想的数学模型.硫分布预测结果指出, 催化汽油的氧化和萃取处理对 汽油脱硫均有贡献, 轻重催化汽油的氧化萃取脱硫没有明显差别. :催化汽油;硫含量分布;数学模拟;氧化脱硫 :T E624.5 　　　　　:A :1006-4 303 (2011)03-0237-04 Simulation of sulfur distribution in catalytic cracking gasoline REN J e, Y UA N H a -kuan (College of Chem cal Eng neer ng and M at er al s S c ence, Z hej ang U n vers t y of T ech nology , H angzhou 310032, Ch na) Abstract:T he s m ulat on of sulfur d st r but o n n cataly t c crack ng gasol ne s carr ed out t hrough the equ l br um d st llat on, measurement of sulf ur co nt ents and mat hemat cal mo dels.T he result s sho w t hat t he heav er d st llates n cataly t c crack ng g asol ne are, the h gher sulf ur cont ent s are .T here s almo st no sulfur n l g ht g asol ne, and m ost sulf ur n res due gaso l ne .T he mat hemat cal model descr b ng sulf ur d st r but o n s est abl shed by deduct ng the model equat o ns and pa ramet ers.T he st at st cal t est result s show that the sulf ur cont ent model (n =1)has h gher prec s on, and t s a bett er mat hem at cal model w hen co mpar ed w th o ther mo dels.T he pred ct o n resul ts show t hat bot h t he ox dat on and ext ract on processes co nt r but e t o the desulf ur zat on, and t here s no d f ference about t he ox dat on and ex t ract o n desulf ur z at on bet ween t he l ght and res due gaso l ne . Key words:cataly t c crack ng gaso l ne;sulfur d str but