镀液中SiC含量对化学镀Ni-P-SiC复合镀层结构和性能的影响.pdfVIP

第26 卷 第4 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol.26 No.4 2014 年7 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Jul. 2014 镀液中SiC 含量对化学镀Ni-P-SiC 复合镀层 结构和性能的影响 王慧龙 窦 勇 傅 强 谭凯元 刘凌云 大连理工大学化学学院 大连 116023 摘要：利用扫描电镜(SEM)、X 射线衍射(XRD) 和腐蚀电化学测试研究了镀液中SiC 含量对化学镀Ni-P-SiC 复 合镀层结构和耐蚀性能的影响。结果表明，随着镀液中SiC 含量的增加，镀层沉积速率和镀层中SiC 共沉积量 呈现先增加后降低的趋势，镀层中P 含量和沉积胞状颗粒尺寸逐渐降低。电化学测试结果表明，镀层中SiC 共 沉积量的变化不影响镀层腐蚀反应机理，但是镀层耐蚀性随SiC 共沉积量的增加而降低。结构分析显示，Ni- P-SiC 镀层致密性良好，基本完全覆盖了镁合金基体。 关键词：AZ91D 镁合金 化学镀 Ni-P 合金 SiC 颗粒 中图分类号：TG 174.44 文献标志码：A 文章编号：1002-6495(2014)04-0307-05 Effect of SiC Content in Plating Bath on Performance of Electroless Plated Ni-P-SiC Composite Coatings on AZ91D Magnesium Alloy WANG Huilong, DOU Yong, FU Qiang, TAN Kaiyuan, LIU Lingyun School of Chemistry, Dalian University of Technology, Dalian 116023, China Abstract: The effect of SiC content in plating bath on the surface morphology and corrosion resis- tance of electroless plated Ni-P-SiC composite coatings on AZ91D magnesium alloy was investigat- ed by means of SEM, XRD and electrochemical corrosion measurements. The results indicate that the deposition rate and SiC content in the Ni-P-SiC composite coatings increase firstly and then de- crease afterwards with the increase of SiC content in the plating bath. The P content and grain size of the composite coatings decrease with the increase of SiC content in the plating bath. The effect of the codeposited SiC on the corrosion process of Ni-P-SiC composite coatings in 3.5%NaCl solu- tion is found negligible, however the corrosion resistance of the Ni-P-SiC composite coatings