纳米ZrO2及低温氧等离子体对真丝织物的复合整理.pdf

dispersion, the analysis showed: after low-temperature plasma treatment, silk fiber’s surface became rough due to the etching effect. After nano-ZrO2 finishing of silk fabrics, nano-ZrO2 particles were uniformly adhered to the surface of silk fibers. Fourier transformation infrared spectrum analysis (FTIR) showed that there were two new absorption peak in 750.84cm-1 and 496.56cm-1 after finishing, and the peak was characteristic peaks of inorganic nano-ZrO .In 1102.13cm-1, there was a new absorption 2 peak, and the peak was characteristic peaks of -Si-O-Si- bonds which was the co-condensation reaction between silane coupling agent and Si-OH of nano-ZrO . And in 2 1713.42cm-1 there was a new absorption peak, the characteristic absorption peak was C=O. So, it indicated that the cross-linking occurs between nano-ZrO2 and silk fiber by coupling agent. X-ray diffraction (XRD) experiment was carried out between original silk fabric and fabric treated by plasma and nano-ZrO2 dispersion. As you can see from diffraction analysis pictures, the main characteristic peak closed to the opposite diffraction angle, indicating that the aggregation structure of silk fabric occurred no fundamental changes when nano-ZrO2 grafted. And the intensity of XRD curves of silk fabric grafted nano-ZrO2 was slightly lower than the original one, which was due to the nano-ZrO2 molecules penetrated into the fibers, weakening the hydrog