数学建模论文--以Eu(TTA)3phen为探针的温敏漆的制备及表征.docVIP

以Eu(TTA)3phen为探针的温敏漆的制备及表征 摘要：本实验以三氯化铕、HTTA、邻菲罗啉为原料合成了Eu(TTA)3phen探针分子，将探针分子与甲基丙烯酸甲酯(MMA)混合后进行聚合，获得了Eu(TTA)3phen/PMMA温敏漆。采用红外光谱（IR）、差热-热重（TG-DTA）、荧光光谱对探针分子的结构和形貌及温敏漆温度猝灭性能进行了一系列测试和表征。红外光谱分析表明：探针分子中Eu3+、HTTA、phen间形成了良好的配位键。TG-DTA分析表明：在285℃以下探针分子能够稳定存在。不同温度下荧光光谱表明，随着温度的升高，温敏漆荧光发射强度逐渐减弱，而最强发射峰波长不随温度变化,均在613 nm左右，说明温敏漆具有良好的温度猝灭特性。 关键词：温敏漆 邻菲罗啉 发光探针分子 PMMA 温度猝灭 Preparation and Properties of Temperature Sensitive Paint Based Upon Eu(TTA)3phen Probe Molecule WANG Yi-ke, YANG Zhi-yun, LI Ji-hong, ZHU Jiu-fu, ZHANG Wen-hao ,SUN Jing* (School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China) Abstract:Using EuCl3,HTTA and phenanthroline as raw materials, the luminescent probe molecules Eu(TTA)3phen were prepared, and then via polymerizing them with methyl-methacrylate (MMA), the temperature sensitive paint (TSP) based upon Eu(TTA)3phen probe molecule was obtained. The structure and properties of the probe molecule samples were examined by IR,TG-DTA and Fluorescence spectrometer.The IR photographs of the probe molecule samples show that there are good coordination bond between Eu3+,HTTA and phen.TG-DTA analysis indicates that, below 285℃, the probe molecule is steady. The fluorescence spectra of the prepared TSP at different temperatures illustrate that the emission strength of the TSP decreases with the increase of temperature, however, at the same time the emission peak position (613nm) keeps no change. It also shows that the TSP based upon Eu(TTA)3phen probe molecule has good temperature quenching property. Key words: temperature sensitive paint；phenanthroline；luminescent probe molecules；PMMA；temperature quenching 0 前言 随着科学技术的不断发展,对测温技术的要求越来越高,温度的测量与控制技术越来越受人们所重视。在国防、军事、科学实验及工、农业生产中,对测温技术的研究已经成为热 作者简介：王艺科（1992 - ），男，河南省许昌人，长春理工大学本科生 *通讯作者：孙晶，博士，教授，主要从事光功能材料化学研究。Sj-cust@126.com 点问题之一。目前,常用的温度测量方法主要有热电偶法、热电阻温度计法等，但是在实际应用中,存在很多特殊条件下的温度测量,例如测试极限温度、高温腐烛性介质温度、气流温度、表面温度、固体内部温度分布、微尺寸目标温度、大空间温度分布等,在这些特殊条件下,实验很难得