水油两相法综述.docVIP

化工进展 水-油两相法制备无机纳米晶自组装结构的研究综述 张育新 董萌 黄明 郝晓东 邱鑫 (重庆大学 材料科学与工程学院，重庆 400044) 摘 要：无机纳米晶自组装结构的合成一直是纳米科学与技术领域研究的热点。本文综述了水-油两相法制备单分散型无机纳米晶、纳米晶自组装薄膜两方面内容，并详细分析了其两相反应机理、晶体生长过程的影响因素、合成条件等。这种水-油两相法合成了包括像金属、半导体纳米材料、光、电、磁、稀土金属等多种无机纳米晶自组装结构，是一种简单并具有一定普适性的制备方法。 关 键 词：水-油两相法; 无机纳米晶; 单分散; 表面改性; 自组装 General Synthesis of Inorganic Nanocrystals Self-assemblies via a Biphasic Method ZHANG YuXin, DONG Meng, HUANG Ming, HAO XiaoDong, QIU Xin (College of Materials Science and Engineering, Chongqing University, Chongqing 400044, P.R. China) Abstract: Assemblied inorganic nanocrystals have attracted much attention in nanoscience and nanotechnology. In this work, a biphasic method is exploited to prepare many kinds of nanocrystals self-assemblies such as monodisperse nanocrystals, self-assembly nanocrystals films. Furthermore, the formation mechanism of self-assembly nanocrystals, synthetic conditions and factors are analyzed, respectively. Generally, this biphasic method is a simple, reproducible and general route, and is becoming a powerful method to prepare many kinds of assemblied nanocrystals including metal, semiconductors, magnetic, dielectric, and rare earth nanocrystals. Key words: a biphasic method; inorganic nanocrystals; monodispersity; surface modification; self-assembly 自组装无机纳米晶作为一种非常重要的纳米材料，它以其独特的物理化学性质，在材料科学、生物、光电等各个领域得到了广泛的关注和研究 ADDIN EN.CITE EndNoteCiteAuthorA.P. Alivisatos /AuthorYear1998/YearRecNum45/RecNumDisplayTextstyle face=superscript[1]/style/DisplayTextrecordrec-number45/rec-numberforeign-keyskey app=EN db-id=xtsz2fxej5srfte5t5ypzfzn5ssdpv5ez5tp45/key/foreign-keysref-type name=Journal Article17/ref-typecontributorsauthorsauthor A.P. Alivisatos , P.F. Barbara, A.W. Castleman , J. Chang /author/authors/contributorstitlestitleFrom molecules to materials:Current trends and future directions/titlesecondary-title Adv. Mater./secondary-title/titlespages1297-1336/pagesvolume10/volumedatesyear1998/year/datesurls/urls/record/Cite/EndNote[ \o A.P. Alivisatos , 19