赢创德固赛无机材料在胶粘剂密封胶中的应用.ppt

* * * * * * * * * * * * * * * * * * * * * * The production of fumed silica began with the discovery of the flame hydrolysis of silicon tetrachloride by Harry Kloepfer in 1943. The intention of this wartime effort was to produce silica that would act as a rubber modifier, then much needed during for tire production. The overall chemistry of the process is quite simple and versatile. A vaporizable metal precursor is fed into a hydrogen/air flame and the hydrolysis product, silicic acid for instance, rapidly condenses to the metal oxide. Multiple pathways to particle formation are possible, such as particle growth through deposition, particle evaporation, aggregation, and aggregate coaggulation. The simplicity of the overall chemistry makes the process very amenable to variation and a diverse array of metal oxides have been produced, some for commerce. Technologies have also been developed that allow mixed metal systems, surface modified particles, doped particle. This allows Degussa to supply material to an unbelievably wide variety of industries and applications. * * P25 = 21 nm; P90 = Dont have data; Alu C = 13 nm * * * * * * Dynasylan? 1146的粘结力表现 试片表面经过擦拭，清洗，冲洗， 在室温下固化14天 Dynasylan? 1146 在杂化体系中作为高效的粘接促进剂 出色的粘接力 Dynasylan? 1146 提供出色的粘接力 胶粘剂/密封胶可以广泛用于 重要的建筑用材料 更好的湿粘性 THANK YOU SUCCESS * * 可编辑 - 40 % ! Dynasylan? 1146 在 MS Polymer? 密封胶中– 低吸水率 Dynasylan? 1146 极大地降低吸水率! 这个测试中, 杂化密封胶浸在 @ 23°C水中 Dynasylan? 1146 在SPUR 密封胶中– 降低吸水率 - 55 % ! Dynasylan? 1146 在SPUR中降低吸水率更加显著！ AEROSIL? 气相法二氧化硅在胶粘剂/密封胶行业的应用 AEROSIL? 生产过程 灼烧法的金属氧化物生产 – ( Harry Kloepfer在1941年发明, 在1943命名为 AEROSIL? 开始商品化生产 – 1953 Al2O3, 1954 TiO2, 1963 疏水级, 1964 AERODISP?) HCl H2O SiCl4 O2 H2 温度 2500°C ? 1000°C 高温水解法生成的金属氧化物 SiCl4 TiX4 AlX3 ZrX4 AEROSIL? 90, 130, 150, 200, 300, 380 二氧化钛 P25 P90 二氧化铝 AluC Alu65 二氧化锆 PH 3YSZ 亲水性 AEROSIL? 气相法二氧化硅 7 7 12 14 20 40 Primary Particle Size [nm] 380 300 200 150 90 50