Se硒同位素地球化学教学课件.ppt

小结 1.生物与非生物的还原反应是导致硒同位素分馏的主要过程，但硒同位素比值只能指示还原反应的发生，而不能判别其反应机理。 2.地表风化过程能够导致硒同位素的显著分馏，但其控制因素仍有待进一步研究。 3.硒同位素在重大地质，大氧化事件以及古海洋硒同位素演化的研究有待开展。 请批评指正！ 30 yrs ago, these areas are low-Se, where Se-deficient diseases was reported in people . Recently, these areas were reported to high-Se areas, but no answer to the reason how to developed. Se deficiency occurs in more than 50 percent of total areas in China. Within geographic low-Se belt, Keshan Disease and Kaschin–Beck Disease were well documented. Rice and corn are staple food to Chinese, cultivating Se-rich rice and corn can greatly improve the status of people Se intake. Se isotopes probably give us some important information on Se uptake by these plants from low-Se soils. 商业产品：HGX-200型氢化物发生系统(只为科研提供参考图片，无广告作用) MC-ICP-MS with Hydride Generator (HG) HR Nu Plasma II HR Nu Plasma Faraday cups Procedures for measuring Se isotopes by Se74-77/82 Double spike Digestion to Se6+, Reduction to Se4+ HG system- H2Se Sample or Standard Measuring Se4+ by HG-AFS Add 74-77Se/74-82Se Double spike 1:1 Double Spike Solution:Isotopically-enriched 74SeIV and 82/77SeIV MC-ICPMS-worksheet Se concentration required 4-5ng/ml ; precision：2σ =0.2‰ Samples purification: TCF or AG1-8 resin 纯化流程见：Rouxel et al., 2002, GCA， Zhu et al. 2008, Chinese J Anal 82 80 78 77 76 74 Operation Interface for Se isotopes measurement 只提供学生了解相关仪器参考使用，不构成方法开发使用依据。 As、Ge干扰监控 During 8 months measurement, NIST SRM3149：δ82/76Se =0.00±0.1‰；Lab’s standard MH495δ82/76SeSRM3149= -3.44±0.1‰； Precision for standard (2σ)： 0.1‰； Precision for samples (2σ)： 0.15‰ Data quality in our lab using 74Se＋77Se double spike Zhu et al. 2008, Chinese J Anal Chem; 2014, GCA Se isotopes in all terrestrial samples are mass-dependant fractionation：δ82/76SeSRM3149＝0.661δ82/78SeSRM3149；and 2σ within 0.2‰ Data quality in our lab using 74Se＋77Se double spike Zhu et al. 2008, Chinese J Anal Chem; 2013, GCA (in press) Native Se crystals 提问与课间休息 三、硒同位素的分馏机制与应用 硒的基本地化性质 Se(s)