photoreaction of adsorbed diiodomethane halide effects of a series of neutral palladium(ii) coordination cages.光反应的一系列卤化吸附二碘甲烷的影响中性钯(ii)协调的笼子.pdfVIP

Dalton Transactions View Article Online PAPER View Journal | View Issue Photoreaction of adsorbed diiodomethane: halide . 6 3 : 5 effects of a series of neutral palladium(II) 1 : Cite this: Dalton Trans., 2016, 45, 1 2 6 9574 coordination cages† 1 0 2 / 2 a a a b c 1 Tae Hwan Noh, Haeri Lee, Doeon Kim, Dohyun Moon, Young-A Lee* and / 0 a 2 n Ok-Sang Jung* o y t i s A series of Pd L -type neutral coordination cages, [Pd X L ] (X− = Cl− and Br−), are constructed via self- r 6 4 6 12 4 e v i assembly of (COD)PdCl and K PdBr with C -symmetric N,N’,N’’-tris(2-pyridinylmethyl)-1,3,5-benzene- n 2 2 4 3 U tricarboxamide (L), respectively. The iodide analogue [Pd I L ] is smoothly synthesized from [Pd Br L ] g