对称双-13恶二唑化合物的合成及性质-化学通报.pdf

化学通报 2015 年 第 78 卷 w2015004 研究论文 对称双-1,3,4-噁二唑化合物的合成及性质 1 2 3 张恒文   李燕萍   李海龙 (1 甘肃工业职业技术学院化工学院 天水 741025 2 新疆大学化学化工学院 乌鲁木齐 830046 3 唐山市质量技术监督局古治区分局 唐山 063100) 摘 要 首先以苯氧乙酰肼和二酰氯为原料反应得到对称双酰肼化合物，再以 POCl3 合环得到系列对称 双-1,3,4-噁二唑化合物。考察了该系列化合物的紫外-可见吸收光谱，其中，间苯双-1,3,4-噁二唑化合物在 250 nm 附近有明显的最大吸收峰，对苯双-1,3,4-噁二唑化合物的最大吸收峰则红移至 290 nm 附近；而脂肪族双-1,3,4- 噁二唑化合物没有明显的最大吸收峰，说明没有大的共轭体系，与结构相符合。所有化合物的结构均经元素分 析、IR 、1H NMR 和 MS 确证。 关键词 1,3,4-噁二唑 合成 表征 Syntheses and Properties of Symmetric Bis-1,3,4-oxadiazoles Zhang Hengwen 1 , Li Yanping 2 , Li Hailong 3 1 2 ( Institute of Chemical Engineering, Gansu Industry Polytechnic College, Tianshui 741025; College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046; 3 The Ancient District Bureau Quality and Technical Supervision in Tangshan, Tangshan 063100) Abstract First of all, phenoxyacetic acid hydrazide and di-acyl chloride are used to synthesize dihydrazide compounds, then a series of symmetric bis-1,3,4-oxadiazoles were synthesized by cyclization with phosphorus oxychloride, and their UV-Vis absorption were studied. UV-Vis maximum absorption peak of m-benzene bis-1,3,4-oxadiazole is located at about 250nm, that of p -benzene bis-1,3,4-oxadiazole shows an obvious red shift, located at about 290nm. Alkanoic bis-1,3,4-oxadiazole did not appear any maximum absorption peak, showing there is no conjugated system in molecule, which is consistent with the its molecular str