循环流化床中含钒石煤料球的焙烧特性试验研究.docxVIP

第29卷第10期 动 第29卷第10期 动 力 工 程 V01．29 2009年10月 Journal of Power Engineering Oct·2009 文章绩号：1000—6761(2009)10—0904—05 孛墨分樊孽：零Q135。1 文激蘸滚羁：A 攀耩努类号：470。10 循环流化床中含钒石煤料球的焙烧特性试验研究 周宛谕， 藐委侩， 王勤辉，徐耀斌 (浙江太学能源清洁和厢国家重点实验塞，杭州310027) 摘要：为避免传统提钒工艺所存在的问题，采用循环流化床钙法焙烧工艺，以添加钙基原料的石 j曩耪臻砖焙烧嚣舞，在热输入功枣为l MW的缓囊：流纯瘩燃烧试验台上进行了含钒石煤焙烧耪眭 试验，霹}究了燃烧稳定注、燃烧效率、污染耪撵葳跨栏、燃烧薏炭渣祷眭和炭渣瓴浸盎特往。结暴衰 明：在以烟煤为助燃燃料的条件下，石煤料球可以在1 MW循环流化床试验台上稳定焙烧运行，展 燃烧效率较高；料球中的锅蕊添加荆有较好的脱硫作用，但对于离硫石煤，要达到国家污染物排放 标准，必须采取尾部烟气脱硫措施；焙烧产物以飞灰为主，飞灰中V205浸出率接近70％，表明循环 流纯廉对菇澡中的甑矿物具蠢是蟹的焙烧氧钱镑臻。 关键谲：疆环流托廉；含钒菇渫耨臻；钙基漆加裁；氧谨焙浇 Calcination Characteristjcs of Vanadium—containing Stone Coal Ball in Circulating Fluidized Bed ZHOU Wan—yu， SHI Zheng-lun，WANG Qin—hui， XU Yao—bin (State Key Lab of Clean Energy Utilization，Zhejiang University，Hangzhou 310027，China) Abstract：To avoid the existing problems in the conventional vanadium extraction processes，the calcium— modified roasting process in circulating fluidized bed was used。Using calcium—based material additive and coal ball roasting material，calcination characteristic8 of vanadium—containing COal was investigated circulating fluidized bed combustion rig with thermal input power of 1 MW．The study included combustion stability，combustion efficiency，pollutant emission characteristics，slag property after combustion well leaching characteristics of vanadium．Results show that the coal ball keep stable roasting operation in i鹾W circulating fluidized bed rig with high combustion efficiency when bituminous coal is used combustion-supporting fuel．The calcium—based additives have good desulphurization effect． But for the stone coal with high sulfur content，installation of flue gas desulfurization(FGD)must be adopted meet the national emission standard．The main roasting product is fly ash，and V2 05 lcaching of fly ash is close 70％，which indicate that the vanadium minerai in coal has good effect roasting oxidation。 Key words：circulating fluidized bed；vanadium—containing stone coal ball}cal