ALCuMn体系600℃锁和500℃等温截面的实验研究.docxVIP

优秀毕业论文 精品参考文献资料 AI—Cu． AI—Cu．Mn体系600 oC和500 oC等温截面的实验研究 摘要 本研究以x一射线衍射(XRD)和配备有能谱仪的扫描电子显微镜 (SE舭DS)的方法，研究A1一Cu-Mn体系600。C和S00 oC全成分范围的 完整等温截面。通过差示扫描量热(DSC)方法，对几个关键合金的液相 线温度和零变量温度进行测定。本研究首次发了现两个新的三元化合物q 和T5。其中，t4一A161．8Cu34．4Mn3．8相成功制备了单相合金，并得到了其XRD 谱线，结构精修结果显示，它是一个面心立方晶体结构，空间群为Fm一3m (NO．225)，晶格参数为a(A)=5．8270393，与A1Cu2Mn(L12)的结构类 型相同。而T，，成功制备了单相合金得到了其XRD谱线，但本文并没有解 析出它的晶体结构。证实了文献报告的4个三元相的存在：T1、T2、仍和13， 其中仍相是只存在于500 oC等温截面，并测定了它们在600。C和500。C 的固溶范围，在600 oC和500。C等温截面，8个二元相A18Mn5、(1BMn)、 A14Cu9、LT—AlllMn4、R-A14Mn、A1Cu一0，A1Cu_rll(A1Cu_r12)禾D A1Cu一5毖 固溶了第三元素；此外我们还测定了固溶体(Cu)的成分范围。 关键词：A1．Cu．Mn体系；等温截面；相图；x．射线衍射(XRD)；扫描电子显 微镜(SEM／EDS)；差示扫描量热(DSC) 毒本课题得到国家自然科学基金项目(No和广西自然科学基金项目(No． 201 1GXNSFF01 8001)对本工作的支持。 万方数据 The The experimental investigation of isothermal section of the AI-Cu—Mn system at 6000C and 5000C ABSTRACT The isothermal section of the A1一Cu—Mn system at 600。C and 500。C were investigated over the whole composition range by means of X—ray diffraction (XRD)，scanning electron microscopy equipped with’energy dispersive X—ray analysis(SEM／EDS)．The liquidus ternpc：a：．．o。and invariant reactions of some key alloys were determined by differential thermal maalysis(DSC)．Two new ternary compoundsi 4 and砧were first discovered in this work．Single—phase alloy for I；4 Was prepared successfully and its XRD pattern Was obtained． q—A161．8Cu34．4Mn3．8 has a Face—centered cubic crystal structure with space group Fm-3m(NO．225)，the lattice constants a=5．8270393(A)，and crystallizes with AICu2Mn structure type．The XRD pattern for zs-A168Cu20Mnl2 was obtained， but its crystal structure has not been determined．Four ternary compound 171，1；2， 173，and p which reported in literature were confirmed in this work and 173 only observed in 5000C．And their homogeneity range at 600。C and 500。C were determinded in this work．Eight binary phases AIsMn5，(13Mn)，A14Cu9， LT-AII IMn4，R-A14Mn，A1Cu_0，A1Cu_q l(AICurl2)and AICu一5 were observed to dissolve the third element．Beside，the solid(Cu)p