以六氟丙烯二聚体为基础的表面活性的合成与性能.docxVIP

第25卷第11期 化学研究与应用 第25卷第11期 化学研究与应用 V01．．25，No．11 2013年11月 Chemical Research and Application Nov．．2013 文章编号：1004—1656(2013)11-1523旬5 I、I—L 匕人／＼ 氟丙烯二聚体为基础的表面活性的合成与性能 杨百勤+，王 林，杨 健，刘 瑾 (陕西科技大学化学与化工学院陕西科技大学教育部轻化工助剂 与技术重点实验室，陕西西安710021) 摘要：以六氟丙烯二聚体为原料，与2一二甲氨基乙胺反应制取了中间体，v，Ⅳ．二甲基-Ⅳ，-(2一三氟甲基-1一五氟 乙基)全氟丙烯基乙二胺，然后分别与四种不同碳链长度的溴代烷烃进行季铵化反应，得到四种季铵盐型含 氟阳离子表面活性剂。经表面张力测试发现四种产物均有较好的表面张力性能，其水溶液的最低表面张力均 接近25 mN·m～，优于传统的碳氢表面活性剂；经接触角测试发现四种含氟表面活性剂均可以将水在PET(对 苯二甲酸乙二醇酯)和石蜡界面上的接触角降低到20。左右，对水在疏水界面上的铺展有很好的促进作用。 探讨了亲水头基大小对该类氟表面活性剂的影响，结果表明改变亲水头基大小对该类氟表面活性剂影响不 大，并通过分析指出对其表面活性和润湿性能起主要作用的是氟碳链疏水端。它们的细微差别可以从疏水基 团的排列形态和溶液表面的吸附状态角度解释。 关键词：氟表面活性剂；六氟丙烯二聚体；阳离子；季铵盐；表面张力；接触角 中图分类号：0647．2 文献标志码：A Synthesis and properties of fluorinated surfactants based on hexafluoropropene dimmer YANG Bat—qin‘，WANG Lin，YANG Jian，LIU Jin (Key Laboratory of Auxiliary ChemistryTechnology for Chemical Industry，Ministry of Education， Shaanxi University of ScienceTechnology，Xi’an 710021 China) Abstract：Intermediate N，N-dimethyl-N’·(2-trifluorometyl一1·pentafluoroethyl)perfluoropropenyl ethane diamine was prepared with hexafluoropropene dimmer and 2-(dimethylamino)ethylamine，which used prepare four quaternary ammonium cationic fluori- nated surfactants with bremoethane，1-bromobutane，1-bromohexane and 1一bromooetane respectively．The results of surface tension measurements indicated that all the four fluorinated surfactants displayed higher surface activity，and the minimum surface tension in aqueous solution were low 25 nan·m～．which Was better than the traditional hydrocarbon surfactants．According to the contact ande measurements，they could reduce the contact angle between water and ethylene terephthalate well paraffin to 200，which was favorable for the spreading of water the two interfaces．The effects of the size of hydrophilic group the performance of these cationic fluorinated surfactants were discussed．It showed that the size of hydrophilic group Was insignificantly to their surface activi- ty while fluorocarbon chains cou