chapter2量子理论的应用.pdfVIP

2 Quantum theory: applications Translational motion To find the properties of systems according to 2.1 A particle in a box quantum mechanics we 2.2 Motion in two and more dimensions need to solve the 2.3 Tunnelling* appropriate Schrödinger equation. Vibrational motion Ch. 2the essentials of 2.4 The energy levels the solutions for three 2.5 The wavefunctions basic types of motion: Rotational motion 2.6 Rotation in two dimensions: the particle on a ring 2.7 Rotation in three dimensions: the particle on a sphere Spin 2.1 A free particle in a one dimensional box ˆ ψ Hψ E I II III 2 2 ˆ  d ˆ H - V x   2m x d 2 2 2  d ψ   2 Vψ Eψ 2md x Region I, III: 2 d ψ 2m   V - E (Vψ 0) V E V     d x2 2 2 2 d ψ h  ψ 0  0 = 0;  l 0