表面修饰硼酸镧纳米粒子的制备及摩擦学性能.docxVIP

第 37 卷 第 12 期Vol. 37 No. 12LUBRICATION EN 第 37 卷 第 12 期 Vol. 37 No. 12 LUBRICATION ENGINEERING DOI: 10. 3969 / j. issn. 0254 － 0150. 2012. 12. 014 表面修饰硼酸镧纳米粒子的制备及摩擦学性能 * 朱 驰 王 玥 周元康 李 屹 吴 兵 ( 贵州大学机械工程学院 贵州贵阳 550025) 摘要: 以 La ( NO3 ) 3 ·6H2 O 和 Na2 B4 O7 ·10H2 O 为原料，添加硅烷偶联剂 KH550，采用化学沉淀法制备出表面被 修饰的硼酸镧纳米粒子; 将制备的纳米颗粒按 2% 的比例加入纯基础油中制备成液固相分散体系，采用透射电子显微镜 对体系的分散性进行表征，采用 MMU-10G 摩擦磨损试验机测试该分散体系对钢摩擦副的摩擦学性能。结果表明: 该润 滑油分散体系具有优异的抗磨性能以及良好的减摩效果，与纯基础油相比，在 250 N、450 r / min 转速下摩擦运行 30 h 的磨损率下降 83% ，摩擦因数下降 30% 。SEM、EDX 分析表明，在摩擦过程中硼酸镧纳米材料参与了摩擦表面的成膜 反应，起到了修复作用。 关键词: 硼酸镧纳米粒子; 表面修饰; 摩擦学性能 中图分类号: TH117 文献标识码: A 文章编号: 0254 － 0150 ( 2012) 12 － 056 － 5 Preparation and Tribological Properties of Surface Modified Lanthanum Borate Nanoparticles Zhu Chi Wang Yue Zhou Yuankang Li Yi Wu Bing ( School of Mechanical Engineering，Guizhou University，Guiyang Guizhou 550025，China) Abstract: Lanthanum borate nanoparticles were prepared by chemical precipitation with La ( NO3 ) 3 · 6H2 O and Na2 B4 O7 ·10H2 O as raw material and modified by silane coupling agent KH550，and a liquid-solid disperse system was formed by adding 2% of the prepared lanthanum borate nanoparticles into the base oil． The dispersiveness of lanthanum borate nanoparticles in the base oil was characterized and analyzed by transmission microscope，and the tribological proper- ties of them as additive were studied on MMU-10G friction and wear testing machine with 45 steel as friction pair． The re- sults show that the prepared lanthanum borate nanoparticles as additive have excellent friction reducing and anti-wear prop- erties，compared with the base oil，the lubricating oil with lanthanum borate nanoparticles can decrease the wear loss of the test sample by 83% and the average friction coefficient by 30% after 30 h friction test under 250 N and 450 r / min． Ac- cording to the SEM，EDX analysis results，lanthanum borate nanoparticles play the role of repairing the friction surface by the film-forming reactio