初始ph对酸性预处理污泥厌氧发酵产氢的影响.docVIP

第29卷第9期2008年9月 环 境 科 学Vol. 29, No. 9Sep. , 2008 初始pH 对酸性预处理污泥厌氧发酵产氢的影响 刘常青, 张江山, 牛冬杰, 陈文花, 赵由才 师范大学环境科学研究所, 福州 350007 摘要:对污泥进行不同p H 值的酸性预处理, 用HCl 将污泥p H 值分别调到2 0、3 0、4 0、5 0, 在4 条件下放置24h, 然后再用NaOH 分别调到2 0~12 0用于批量试验, 系统考察了不同初始p H 值对酸性预处理污泥厌氧发酵产氢的影响. 研究表明, 初始p H 为2 0~4 0以及12 0时对产氢菌及耗氢菌有抑制作用, 总体产氢量少; 初始pH 为5 0~9 0时, 甲烷菌及产氢菌均活跃, 产氢滞后时间短, 但总体产氢量少; 初始p H 为11 0时, 甲烷菌受到明显抑制, 而产氢菌仍然活跃, 总体产氢量较高, 发酵后期pH 恒定在7 0~8 0, 经p H 为2 0、3 0、4 0和5 0酸性预处理的污泥(干重 累积产氢量分别为0 59、1 83、0 50和0 56mL g. 关键词:市政污泥; 酸处理; 生物产氢; 厌氧发酵; pH 中图分类号:X705; X382 1 文献标识码:A 文章编号:0250 3301(200809 2628 05 1, 2 3* 1 3 1 (1 同济大学污染控制与资源化研究国家重点实验室, 上海 200092; 2 福建师范大学地理科学学院, 福州 350007; 3 福建 Effects of Initial pH on Hydrogen Production from Acid Pretreated Municipal Sludge LI U Chang qing , ZHANG Jiang shan , NI U Dong jie , CHEN Wen hua , Z HAO You cai 1, 2 3 1 3 1 (1 State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, T ongji Uni versity, Shanghai 200092, China; 2 School of Geographical Science, Fujian Normal Universi ty, Fuzhou 350007, China; 3 Insti tute of Environment Protection Science, Fujian Normal University, Fuzhou 350007, China Abstract :A series of batch tests were conducted to investigate the effects of initial pH on bio hydrogen production from acid pretreated municipal sludge. The p H of sludge was first adjusted to 2 0, 3 0, 4 0and 5 0, s tood by for 24h in a refrigerator at 4 , then adjusted to pH 2 0 12 0respectively before using as the substrates for batch experiments. The results showed that the acid pretreated sludge wi th initial pH 11 0gave the highes t hydrogen production, and the corresponding accumulative hydrogen for sludge(dry basis pretreated at p H 2 0, 3 0, 4 0and 5 0were 0 59, 1 83, 0 50and 0 56mL g respectively. Hence, i t could be seen that the initial pH 11 0for the acid pretreated sludge should be the opti mu m pH range for promotin g the growth of dominant hydrogen producing anaerobes, while inhi biting hydrogen consuming anae