《硫化亚铜催化乙炔合成纳米碳纤维的研究》-毕业论文（设计）.docVIP

硫化亚铜催化乙炔合成纳米碳纤维的研究 摘 要 纳米碳纤维具有非常优异的导电性、电化学性能及机械性能，目前已经应用于许多领域，如场发射显示器，二次电池电极以及复合材料等领域。 本文研究了以乙炔（C2H2）为碳源，以水热合成在铜基体上的硫化亚铜薄层为催化剂，采用化学气相沉积法（CVD），制备纳米碳纤维。利用场发射扫描电子显微镜（FE-SEM）、X射线衍射仪（XRD）对所得产物进行了表征，并分析了实验条件对纳米碳纤维产量的影响。结果表明，水热法可以在铜基体上合成纳米级硫化亚铜颗粒，制得的硫化亚铜颗粒在合成纳米碳纤维方面具有良好的催化作用，制备的纳米碳纤维呈非晶态。硫化亚铜催化剂制备过程中，随着水热反应时间的增加，纳米碳纤维的产率逐渐增加，并趋于一个极大值；合成纳米碳纤维过程中，随着反应时间增加，纳米碳纤维的产率呈线性增加。 关键词：硫化亚铜；CVD；水热法；乙炔；纳米碳纤维  RESEARCH ON THE CNFs SYNTHESIS OF ACETYLENE CATALYZED BY CUPROUS SULFIDE ABSTRACT Carbon nanofibers (CNFs) have many unique properties such as electrical conductivity, electrochemical property and mechanical property. Many applications are being developed for ?eld-emission display, electrodes of secondary battery and composites, etc. In this paper, CNFs were synthesized by using chemical vapor deposition (CVD) with cuprous sulfide which is synthesized by hydrothermal method on copper substrate as catalyst and acetylene as carbon source. The products were characterized by FE-SEM and XRD. The influences of experimental conditions on the yield of CNFs were also investigated.The results indicate that it is practicable to prepare cuprous sulfide nano-particles on the copper substrate by hydrothermal method. The synthesized cuprous sulfide particles exhibit good catalytic property in the synthesis of CNFs, and the prepared CNFs has amorphous structure. In the preparation of cuprous sulfide nano-particles, the yields of CNFs gradually increase with the increase of hydrothermal reaction time, and tend to a maximum. In the synthesis of CNFs, the yields of CNFs increase linearly with the increase of reaction time. KEY WORDS: cuprous sulfide; CVD; hydrothermal; acetylene; CNFs 目录 TOC \h \z \t 论文正文章标题,1,论文正文节标题,2,论文正文小节标题,3,论文正文小节子标题,4,参考文献标题,1,致谢标题,1 前言 1 1文献综述 2 1.1碳纳米管简介 2 1.2碳纳米管的制备 2 1.2.1电弧法 2 1.2.2激光蒸发法 3 1.2.3化学气相沉积法 4 1.3纳米碳纤维生长机理 6 1.4碳纳米管的性能 7 1.4.1力学性能 7 1.4.2热学性能 7 1.4.3场发射性能 8 1.5碳纳米管的应用 8 1.5.1碳纳米管/金属基与高分子基复合材料 8 1.5.2 碳纳米管压制体—超