常用有机膦酸盐静态阻垢性能对比实验研究.docVIP

第1卷　第2期环境工程学报 Vol.1,No.22007年2月 Chinese Journal of Envir on mental Engineering Feb.2007 常用有机膦酸盐静态阻垢性能对比实验研究 徐华山1 　任玉芬 1,23 　贺玉晓1　郑红娟 3 (1.河南理工大学资源环境学院,焦作454000;2.中国科学院生态环境研究中心,系统生态国家重点实验室,北京100085; 3.北京中搜网络技术有限公司苏州分公司,苏州215000 摘　要　工业冷却水循环利用过程中,随浓缩倍数提高,循环水水质向高碱度、高硬度、高pH 值和高温方向发展,结垢倾向严重。聚磷酸盐和有机膦酸盐是性能优良的钙垢抑制剂,但在高温、高浓缩倍数条件下时,有机膦酸盐类不见得均可达良好的水垢抑制效果。分别计算了氨基三亚甲基膦酸(AT MP 、羟基亚乙基二膦酰(HE DP 、22膦酸丁烷21,2,42三羧酸(P BT C 和六偏磷酸钠(NaP O 36在循环水浓缩倍数为1~5倍,温度为80℃时在不同投加浓度下的阻垢率。结果表明,有机膦酸盐和聚磷均有临界值效应;有机膦酸盐的阻垢性能优于聚磷酸盐;AT M P 和HE DP 在低浓缩倍数下有较高的阻垢率,随着硬度、碱度、pH 值的提高,阻垢率下降明显;P BTC 的水垢抑制剂功效明显优于其他有机膦酸盐,P BT C 可应用在较宽广的水质操作范围,增加系统的操作安全性。 关键词　循环冷却水　有机膦酸盐　阻垢 中图分类号　T Q085.412　　文献标识码　A 　　文章编号　167329108(2007022******* Co m par ison of st a ti c sca le 2i n h i b iti n g properti es of typ i c organo 2phosphona te Xu Huashan 1 　Ren Yufen 1,2 　He Yuxiao 1　Zheng Hongjuan 3 (1.College of Res ources and Envir onment,Henan Polytechnic University,J iaozuo 454000; 2.Nati onal Key Laborat ory of Syste m s Ecol ogy,Research Center for Eco 2Envir onmental Sciences, Chinese Acade my of Sciences,Beijing 100085; 3.Suzhou B ranch Company,Beijing Zhongs ou Net w ork Technique L td .,Suzhou 215000 Abstract 　During the usage of the industrial cooling water,as the concentrati on multi p le increases,it enri 2ches alkalinity,hardness,pH and te mperature and scales seri ously .Polyphos phate and organo 2phos phonate are good calciu m scale inhibit ors .But under high te mperature and highly enriched concentrati on of circulating water,not all organo 2phos phonates can reach the sa me efficiency of scale p reventi on .The paper calculated the scale p re 2venting efficiency of a m ino (tris methyl enephos phonic acid (AT MP ,12hydr oxyethylidene 21,12di phos ph 2oni 2cacid (HEDP ,22phos phonobutane 21,2,42tricarboxylic acid (P BTC and (NaP O 36when the concentrati on multi p les are fr om 1t o 5,the te mperature is 80℃and their consistencies are different .The results show that both organo 2phos phonate and polyphos phate have the t