铸态 Ti-Zr-Ni 准晶的贮氢特性.doc

第18卷第1期中国有色金属学报2008年1月V ol.18 No.1The Chinese Journal of Nonferrous Metals Jan. 2008文章编号:1004-0609(200801-0108-05 铸态Ti-Zr-Ni准晶的贮氢特性 黄火根1,银陈1,吴江2,张鹏程3 (1. 表面物理与化学国家重点实验室,绵阳 621907; 2. 大连理工大学材料科学与工程学院,大连 116024; 3. 中国工程物理研究院,绵阳 621900 摘要:研究铸态Ti-Zr-Ni准晶体的贮氢特性。Ti40Zr40Ni20合金在吸铸条件下形成了近单一的二十面体准晶相(IQC 相,其吸氢坪台压力在170 ℃时约20 kPa,160 ℃时只有0.6 kPa,吸氢量为0.8%(质量分数;而Ti45Zr38Ni17合金在同样条件下则形成了IQC、MgZn2结构的C14 Laves相与体心立方结构的β-(Ti, Zr固溶相,它可实现室温贮氢,150 ℃时贮氢量达到4%,且具有较好的吸氢动力学。结果表明,合金成分与制备方法对Ti-Zr-Ni准晶的贮氢特性有较大影响。 关键词:Ti-Zr-Ni合金;准晶;贮氢;吸铸 中图分类号:TG 139.7文献标识码:A Hydrogen storage of as-cast Ti-Zr-Ni quasicrystals HUANG Huo-gen1, YIN Chen1, WU Jiang2, ZHANG Peng-cheng3 (1. National Key Laboratory for Surface Physics and Chemistry, Mianyang 621907, China; 2. School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China; 3. China Academy of Engineering Physics, Mianyang 621900, China Abstract: Hydrogen storage characteristics of quasicrystalline alloys Ti40Zr40Ni20 and Ti45Zr38Ni17 prepared by suction-casting method were investigated primarily. Ti40Zr40Ni20 alloy, in which a nearly pure icosahedral quasicrystal (IQC phase can form, has a low H-absorbing capacity of 0.8% (mass fraction and different plateau pressures at different temperatures, 20 kPa at 170 ℃ and 0.6 kPa at 160 ℃, respectively. However, a minor mixture of C14 Laves (MgZn2-type and β-(Ti, Zr solution (bcc structure phases is coexisted with the IQC in Ti45Zr38Ni17 alloy that can load H at room temperature with a maximum storage of 4% at 150 ℃and displayed good H-absorption dynamic behaviors, suggesting a promising future as new H-absorbing material. The results show that the alloy composition and preparation of Ti-Zr-Ni IQC have a significant effect on its H storage. Key words: Ti-Zr-Ni alloy; quasicrystal; hydrogen storage; suction-casting 准晶是一种具有非晶体学旋转对称性的准周期长程平移有序相[1],其特殊结构决定了它的一系列独特性能及其潜在的实用性[2]。早期准晶的合金组元与氢亲和力较小,因而当时人们没有认识到准晶的可贮氢性。直到首例Ti-Zr-Ni准晶[3]被报道,人们才开始关注准晶的贮氢性能。因为Ti-Zr-Ni准晶是一个典型的稳定二十面体准晶系,其结构中