分体式膜-生物反应器在废水处理中的工艺条件.docVIP

分体式膜2生物反应器在废水处理中的工艺条件 吕红,徐又一3,朱宝库,徐志康,谢柏明(浙江大学高分子科学与工程学系,杭州　310027 摘要:对分体式膜2生物反应器(RMBR 处理废水进行了研究.进水COD Cr :312~584mg/L ,RMBR 的出水COD Cr 在运行4d 后15mg/L 并稳定.向生物反应器添加015g/L (混合液的粉末活性炭(PAC 后出水COD Cr 4122mg/L.膜侧污水流速在019~119m/s 范围内,临界膜通量随膜侧污水流速的增大而增大.添加PAC ,组合添 加PAC 和Al 2(SO 43?18H 2O 均可有效提高临界膜通量.在膜侧流速119m/s 的条件下,临界膜通量从72L/(m 2? h 分别增至76L/(m 2?h 和81L/(m 2?h .在22℃~30℃范围内,每升高1℃可提高膜通量119%.在连续运行100d 中,RMBR 可在无任何物理,化学清洗的条件下运行14d 而透膜压力无增大,膜通量不降低.对于已污染的 膜,水清洗、水碱共同清洗、水碱酸共同清洗可分别恢复至新膜膜通量的47%、83%、94%.关键词:分体式膜2生物反应器;污水处理;膜污染;临界膜通量 中图分类号:X70313　文献标识码:A 　文章编号:025023301(20030320420061 基金项目:国家自然科学基金资助项目作者简介:吕红(1972~,男,硕士生,工程师,主要从事污水 处理与高分子材料方面的研究. 收稿日期:2002206227;修订日期:2002209216 3通讯联系人 Processing Conditions of R ecirculated MBR for W aste w ater T reatment L üHong ,Xu Y ouyi ,Zhu Baoku ,Xu Zhikang ,Xie Boming (Department of Polymer Science and Engineer 2 ing ,Zhejiang University ,Hangzhou 　310027,China Abstract :In this paper ,wastewater was treated with Recirculated Membrane Bio 2Reactor (RMBR and effluent quality became stable after four days running continuously.Critical membrane flux was increased with increasing crossflow ve 2locity between 019~119m/s.Under crossflow velocity of 119m/s ,critical membrane flux was enhanced from 72L/(m 2?h to 76L/(m 2?h or 81L/(m 2?h respectively when powdered activated carbon (PAC or both PAC and alum were added to the system.Between 22℃~30℃,the flux was elevated 119%per 1℃increased.Fouling materials were re 2moved efficiently through cleaning physically or/and chemically with flux recovery of 47%~94%. K eyw ords :recirculated membrane bioreactor ;wastewater treatment ;membrane foulin g ;critical membrane flux 　　膜2生物反应器(Membrane Bio 2Reactor ,MBR 是将膜和活性污泥相结合的一种污水处理技术.同传统的活性污泥法相比,MBR 具有许多优点[1~4].按膜和生物反应器的位置关系可将MBR 分为分体式和一体式2种.分体式膜2生物反应器(Recirculated Membrane Bio 2Reactor ,RMBR 是将膜组件与生物反应器分 置,由泵将混合液加压送至膜组件,浓缩液循环 回生物反应器,滤过液作为出水;一体式膜2生物反应器(Submergered Membrane Bio 2Reactor ,SMBR 是将膜组件浸没于生物反应器中,通过负压抽吸或虹吸得到过滤液.在RMBR 中,为了延缓膜污染,膜侧废水流速一般为2~5m/s , 导致