硝酸银溶液性质对超细银粉形貌与粒径的影响_郭学益.pdfVIP

18 6 2013 12 Vol.18 No.6 Materials Science and Engineering of Powder Metallurgy Dec. 2013 ( 410083) AgNO3 ζ –c(AgNO3)pH c(AgNO3) 0.30 mol/L pH pH 7.0 c(AgNO3)0.2 mol/LpH=5.0 AgNO3 PVP 80PEGPAA pH TF123.7+2 A 1673-0224(2013)6-912-08 Effect of AgNO solution property on morphology and 3 grain size of ultrafine silver powder GUO Xue-yi, JIAO Cui-yan, DENG Duo, TIAN Qin-hua, YI Yu (School of Metallurgy and Environment, Central South University, Changsha 410083, China) Abstract: The dispersive ultrafine silver particles were prepared by the reduction of AgNO3 with ascorbic acid as reducer. The properties of the ultrafine silver powders were characterized by scanning electron microscope (SEM), ζ potential analyzer and ultraviolet-visible absorption spectrum analyzer (UV-VIS). The effects of concentration, the initial pH value and the addition of the surfactant on the morphology and size of the silver particles were investigated. The results show that, when c (AgNO3) 0.30 mol/L, the prepared silver powders show rough surface, irregular morphology and worse dispersity. The particle size of silver powder decreases with increasing initial AgNO pH value, however, when the initial 3 AgNO3 pH value is 7, the silver powder aggregate severely. The dispersive spherical silver particles with smooth surface can be prepared with the initial AgNO3 pH value of 5.0, concentration of less than 0.2 mol/L by the rapid addition of ascorbic acid without the addition of surfactant. It is deduced that the ascorbic acid plays