天津大学期末试卷.pdfVIP

16 20 20 A B 20 1. 2. BC 3. / 4. i 5. 6. K 7. Wilson NRTL 8. 1. Lewis-Randell 2. 5 1. 473 K30×10 Pa Hm=? -5 3 -1 pV =RT+10 p p PaV m ·mol m m id -3 -1 -1 C = 7.0+1.0× 10 T (J·mol ·K ) p 273 K Hm=0 (J·mol-1) A=20.7 B=2219.2C=-31.13p PaTK z =1 2 3 ˆ ˆ 2. 1 f 40x −60x +30x f 1 1 1 1 1 (1) 1 f 1∗ (2) 1 Henry k1 (3) x 1 γ Lewis-Randell 1 (4) x 1 γ Henry ′ 1 3. V −V a + (b −a )x −bx 2 1 1 1 1 V −V a + (b −a )x −bx 2 2 2 2 2 V V ab Tp 1 2 4. y , y ,….,y Tp 1 2 n x , x , ….x 1 2 n