生物发酵工艺,合成气生产乙醇.doc

Syngas to Ethanol Process via Bacterial Fermentation 合成气生物发酵制乙醇工艺开辟 煤制乙醇新路线 Mark Niederschulte 2017 Coal/Syngas to Ethanol Conference 2017 煤/合成气制乙醇技术与市场论坛 October 19, 2017 Fueling a Cleaner Tomorrow Jupeng Bio History 巨鹏生物发展历程 1989 – Core syngas fermentation technology discovery 发现核心合成气发酵技术 2003 – Integrated gasification – fermentation pilot demonstration 气化加发酵一体化小试装置 2008 – INEOS Bio created 设立英力士生物公司 2011 – INEOS Bio JV Chosen for $50m Grant from the U.S. Department of Energy 获得美国能源部5000万美元补贴 2011 – INEOS Bio JV Closes $75m in Financing Under U.S. Department of Agriculture Loan Guarantee Program 获得美国农业部7500万美元贷款担保 2012 – INEOS Bio Facility Receives Registrations from U.S. EPA for production and Sale of Next Generation Cellulosic Ethanol 通过美国环保署的注册认证获准生产和销售新一代纤维素乙醇 2013 – INEOS Bio Produces Cellulosic Ethanol At Commercial Scale 实现商业规模生产纤维素乙醇 2017 – Jupeng Bio acquisition of INEOS Bio 英力士生物并入巨鹏生物 2 Jupeng Bio Syngas Fermentation Process Technology Converting Coal Based Syngas to Ethanol 巨鹏生物发酵法合成气制乙醇工艺 ? Fermentation using a naturally occurring organism 自然界细菌，生物发酵路线 ? Tolerant to wide range of syngas compositions 对合成气组分变化具有高宽容性 ? 90% CO conversion, 98% ethanol selectivity 一氧化碳转化率为90%；乙醇选择性为98% ? Bacteria generates H 2 from H2O via water- 2 from H2O via water- gas shift reaction 水中取氢（细菌法水气变换） ? CO-rich syngas preferred尤其适合富一氧化碳 的合成气 Coal based syngas 煤制合成气 发酵 蒸馏 Fermentation Distillation 脱水 Dehydration 水循环 Water Recycle Ethanol 乙醇 3 Jupeng Bio Technology Process Development 巨鹏生物技术发展历程 ? Production of ethanol from syngas has been studied for 17 years at pilot plant scale 启动小试装置，研究合成气制乙醇工艺，至今已有17年 ? 110,000 hours of run time 运行时间共110，000小时 ? 24 kta demonstration plant in USA operated for 4 years 美国2.4万吨/年示范工厂运行4年 ? 750 m3 CSTR fermenter and 3 fermenter growth train 750 m3 连续搅拌式发酵塔，带3个发酵生产罐 ? Combined run time of over 40,000 hours 一体化装置运行时间4万多小时 ? Longest continuous fermenter run was 300 days 发酵塔连续运行最长达 300天 4 Jupeng Bio Technology Process Development 巨鹏生物技术发展历程 ? INEO