HVOF喷涂Fe基非晶合金涂层的组织结构和耐腐蚀性能.docVIP

第1卷第1期 热喷涂技术 V01.1No.1 :竺!生2旦 坠翌翌!iP量坚!璧墅212碰 兰业::兰唑 HVOF喷涂Fe基非晶合金涂层的 组织结构和耐腐蚀性能★ 崔崇,叶福兴,兰学文,杨雪 (天津大学材料科学与工程学院,天津300072 摘要:采用超音速火焰喷涂技术,制备了含Fe、Cr、Mo、Ni、P、Si、B的Fe基非晶合金涂层。利 用显微硬度计、扫描电子显微镜、x射线衍射仪、电化学工作站、差示扫描量热仪等设备对涂层的组 织结构、耐腐蚀性能和热稳定性进行了研究。喷涂工艺参数为:氧气压力0.6MPa,氧气流量166L?rain1, 丙烷压力0.55MPa,丙烷流量24L?rain-I,喷涂距离350ram。制备的涂层孔隙率和显微硬度分别为1.8% 和823HV0.1,其非晶化程度较高;微观结构分析表明涂层由熔化变形成扁平粒子、未熔化的粉末颗粒 以及孔隙、裂纹等缺陷组成的波浪层状组织。相组织结构分析表明涂层丰要由非晶相组成,含有少量 的纳米晶相组织。差示扫描量热仪测试表明所制备涂层的晶化区间为532℃~580℃。电化学测试表明, Fe基非晶合金涂层在lmol?Lo的H2s04、10%NaOH和3.5%NaCI溶液中都经历了活性溶解—钝化一 过钝化的过程,涂层在NaOH溶液中的耐腐蚀性能最强,其次为NaCI溶液,在H2S04溶液中的耐腐 蚀性能较差。 关键词:超音速火焰喷涂;非晶合金涂层;铁基合金;显微硬度;耐腐蚀 中图分类号:TGl74.4文献标识码:A 文章编号:1674-7127(2009Ol-0049.04 Structure and Corrosion Properties of Fe—based Amorphous Coatings Deposited by HVOF CUI Chong,YE Fu—xing, (School of Materials ScienceEngineering, Lan Xue—wen,Yang Xue Tianjin University,Tianjin 300072,China Abstract:Fe-based amorphous alloy coating(Containing Fe,Cr,Mo,Ni,P,Si,Bwas deposited by High Velocity Oxy.Fuel(HVOFtechnique.The structure,corrosion resistance and thermal stability ofthe deposited coating were investigated by recalls of microhardness tester,optical metallographic microscopy(OM,X—ray diffraction(XRD,scanning electron microscopy(SEM,corrosion resistance evaluation set-up,differential scanning calorimetry(DSC.Through orthogonal experimental design,the optimized were obtained.The parameters of spraying is 02pressure was 0.6MPa,the 02flow rate was 166L‘min-1,the C3H8pressure was 0.6 MPa,the C3H8flow rate was 24L?mill-1and stand—off distance Was 350mill.The porosity of deposited coating was嬲low as 1.8%the microhardness was as high as 823HV0.1.A dense,homogeneous and lamellar coatings with high fraction of amorphous phase was obtained,which was composed of deformed strip shaped particles, ’清华大学先进成形制造重点实验室开放基金项目(2008006;天津市应用基础研究计划项目(07JCYBJCl8200;国家自然 科学基金项目作者简介:崔崇(1984一,男,河北人,博士研究生.Email:cuichong@yahoo.on ?50? 热喷涂技术 l卷 an.melted particles,some pores and cracks.The DSC test showed that