aao模板合成介孔zro2纳米线及其光致发光性能.pdfVIP

阳极氧化铝模板合成介孔ZrO2 纳米线及光致发光性能 摘 要：以 AAO 为模板，把模板的纳米孔洞作为微腔反应器，以 P123 为致孔剂，氧氯化锆为锆源 和无水乙醇为溶剂合成前躯体，采用压力诱导的方法将前躯体注入到 AAO 孔道内，经加热处理后， 在模板的纳米孔洞内合成了具有介孔结构的一维 ZrO2 纳米材料。通过 SEM、TEM、XRD 、EDS 和 N2 吸附-脱附进行表征，结果表明：所合成的介孔 ZrO2 纳米线具有介孔结构和较大的比表面积，并 考察了相应的光致发光性能。 关键词：阳极氧化铝；模板法；介孔 ZrO ；纳米线；光致发光性能 2 The Aynthesis and Photoluminescence Property of Mesoporous ZrO2 Nanowires by the Anodic Alumina Template Lü Ren-jiang ，Hou Xue-gong ，Li Ying-jie* ，Deng Lei ，Ding Hui-min ，Ding Shuang (Chemistry and Chemical Engineering Institute of Qiqihar University，Qiqihar 161006) Abstract The AAO membrane acting as templates, the nano-channels of AAO template were used as micro-cavity reactor. The precursor was prepared with the P123 as porogen, ZrOCl as the zirconium source and ethanol as the solvent. The precursor was assembled into AAO nano-channels by the vacuuming and pressure-induced technique. After the heat treatment, one-dimensional ZrO2 nanomaterials with mesoporous structure were fabricated within the nano-holes of AAO template. The obtained samples were characterized in detail by SEM, TEM, XRD, EDS and N sorption and desorption. The results showed that 2 the mesoporous ZrO2 nanowires had better mesopore structure and high surface area, and owned good photoluminescence property. Keywords Anodic aluminium oxide; Template technique; Mesoporous ZrO ; Nanowires; 2 Photoluminescence property 介孔材料由于在其尺寸上具有微观性，因而具有特异的光、电、磁等特性。在太阳能转化、纳 米器件研制、催化剂、介观领域等方面有着宽广的应用前景[1-3] 。ZrO2 是一种重要的无机功能材料， 具有优异的物理和化学性质，是唯一同时具有表面酸性位和碱性位的过渡金属氧化物，具有抗热性 强、耐高温、化学稳定性好、材料复合性突出等特点[4-6] 。将纳米 ZrO2 与其他纳米材料组成复合材 料，能极大地提高材料的性能参数、抗弯强度、断裂韧性等。纳米氧化锆粉体在国防、电子、高温 结构和功能陶瓷，尤其是在表面涂层等高科技领域有重要应用价值[7,8] 。 有关介孔二氧化锆的合成方法表现出多