磁性纳米粒子的合成、功能化及应用.ppt

Figure 7. A) TEM image showing 3–6 nm FePt particles in a carbon matrix. B) High-resolution TEM image showing isolated FePt particles encapsulated in partially spheroidal graphitic coatings with an interlayer separation of 0.345nm Figure 6. XRD and calculated particle diameters of assynthesized FePt, non-encapsulated FePt, and carbon-encapsulated FePt Figure 8. Magnetic hysteresis observed in a glucose@FePt (1:1) sample as compared with the weak superparamagnetic properties with no hysteresis (signal amplified 20 times) observed in glucose@FePt (1:4). Figure 1. Schematic illustration of magnetic silica spheres coated with an outer shell of gold. Au coated Figure 2. TEM images of silica-coated magnetite/maghemite nanoparticles forming magnetic silica spheres. Figure 4. TEM images of the gold shells (right) formed on the magnetic silica spheres Chem. Mater. 2006, 18, 2701-2706 Precious-Mental coating Zhihui Ban, et al. J. Mater. Chem., 2005, 15, 4660–4662 Fig. 1 (a–c) TEM micrograph and XRD of iron coated with gold nanoparticle,about 16 nm. Fig. 2 HRTEM of Fe@Au nanoparticles (a,c) showing the fringes of crystal planes for gold shell, 2.4 A°(111)and crystal planes for iron core, 2.0A°{110} Magnetic NPs Application of Magnetic Nanoparticles Catalysis New applications Ferrofluid Other Applications Such as Medicine Information Storage Biotechnology Applications in Catalysis Scheme 2. Suzuki cross-coupling reaction of an aryl halide and an arylboronic acid in dimethylsulfoxide The result of the catalytic reactions revealed that fresh Ni nanoparticles had such good reactivity that even reactions conducted using aryl bromides proceeded with 98% yield.In contrast, when we tried to reuse the nanoparticles for the catalytic reaction,the yield decreased significantly to 47%. Taeghwan Hyeon, et al;Adv.Mater.Vol.17,429,2003 Figure 1.TEM images of a)2nm,b)5nm,and c)7nm sized Ni nanoparticles.and Figure TEM image of suprelattices of 5nm sized Ni nanoparticles Robin B. Be