碘催化有机化学反应.pptVIP

The Applications of lodine as Catalyst in Organic Reaction Content The formation and cleavage of ether bond Acyl reaction Addition reaction Oxidation reaction Reductive reaction Rearrangement reaction 碘处于元素周期表第ⅦA族的最下端,具有 较大的原子半径和多层电子结构,使它除具 有该族元素的通性外,还具有一定的特殊性 质,如能催化有机化学反应,因而受到有机化 学界的重视 醚键的形成和断裂 MeOHnz CHIOMe)z L2.40 min hexane, reflux Scheme 2 Sclee 2 J.Oa.chem.2001,66,7527-7529