金属有机框架复合材料制备及应用.pptVIP

色中围术 金属有机框架复合物的 制备及其应用 成员名单: 丁美丽(组长) 杨其浩,蔡国瑞,焦龙,关艳芳,汪雯岚,王婷, 刘雅婷,胡灿宇,武迪,闵迪,刘东,王瑶  糖●草  Thin film POMs QD \Enzymes MOF CNTs Polymers Graphenes Oxides Metal NPs  MOF-Metal nanoparticle 1. Solution infiltration method ship in bottle Angew. Chem., Int Ed, 2008, 47, 4144-4148  Angew. Chem., Int Ed, 2005, 44, 1261-1265  2. Gas phase infiltration method MOF-5 cage blue/yellow) with our incorporated n -C3H5/Pd(m-C:H5) sors (red). The elemental cell of the crystalline MoF-5 contans eight of this kind. Reprinted with permission from ref s 2IF-s Fig 6 Schematc illustration of preparation of Ni@zIF-8 from ZIF-8 via gas phase loading of nickelocene followed by hydrogen reduction. Reprinted vith permission from ref. 102 Angew.chem,lnt.Ed.,2005,44,6237-6241 Chem. Commun,2012,483173-3175  3. Solvent-free solid grinding method Me Au Clusters on PCP IxIng H. Reduction 120°C Solid Grinding Chem.-Eu:J.,2008,14,8456-8460  4. Template synthesis method ●●●● Nat.Chem.,2012,4,310316 J.Am.Chem.Soc,2012,134,14345-14348  5. Functional applications ah「 ,,m..n AUOMIL-10 N@ML-101 J.Am.Chem.Soc,2012,134,7211-7214. AuNi@_a n|1.Anm, Chem. Soc.,2013135,1021010213 100120140 Chem.SOC.Rev,2012,41,5262-5284 Time(min  MOF-Metal oxide composites 1. Metal-oxide-NP@ MOF nanocomposites 5um Fi. 2 SEMiinaresef the NiFe O fiba(al NiFe O FC after 24h ours teaction bl; zo tied imge afan edge partially aanbedfing NiFe- O fiber le: CaFe 0. FCsafler itasienals of Zn Fe and Ni naled respectively to the metals of MOF-5 and NiFe, O, fibers (h) o the same an reveal d b J. Mater.Chem.,2012,22,11470-11474