安庆市区及周边地区表层土壤多环芳烃浓度特征、源解析及风险评价.pdfVIP

安庆师范大学硕士学位论文 （4）生态风险评价的结果表明，以毒性当量因子为评价方法时，采用苯并(a) 芘的毒性当量浓度法进行生态风险评价，绝大部分点位处于目标参考值以下，故 可认为安庆市区及周边部分县市区域土壤中毒性当量整体处于正常水平；在以效 应区间低、中值法为评价方法对安庆及周边地区的样点土壤进行生态风险评价 后，结果显示，在所有样点采集的85个表层土壤的样品中的多环芳烃，没有超 ERM 过生态风险效应中值 （ ），总体而言，安庆市区及周边显示的部分区域的 表层土壤产生负面生态效应的几率较小，但 InP、BbF、BkF、BghiP 可能会引起 负面生态效应。 （5）安庆市区及周边地区表层土壤多环芳烃含量基本都低于土壤中PAHs 污染物的二级标准限值含量，大部分样点区域处于无污染，应切实预放，少数点 有个别多环芳烃的含量超过二级标准，属于轻度污染，存在潜在污染风险，应扩 大研究面积深入详查。 （6）综合致癌贡献率较高的Bap 与DaA 含量在进行致癌风险分析，绝大部 分的样品含量土壤都低于我国土壤标准与加拿大土壤标准，总体上看，采集的 85个安庆及周边地区的表层土壤大部分样点区域处于无污染，致癌风险较小， 对人体影响较小，但仍有部分点位需进行预防治理。 关键词：安庆 表层土壤 多环芳烃 来源 浓度分布 风险评价 7 Abstract Abstract From may to July in 2019 in anqing city and the surrounding counties and cities area (in Huaining county, Anqing city, Tongling region, Chizhou region) of the communistparty of China acquisition 85 surface soil (mainly based on farmland soil), on the content of polycyclic aromatic hydrocarbons in the soil, distribution characteristics and potential sources are analyzed, at the same time the environment ecological risk is assessed. In this paper, soil samples were extracted by accelerated solvent extraction method,andpurifiedby silica gel alumina column (filledwith 2 cm anhydrous sodium sulfate, 1cm copper powder, 10 cm silica gel, 5 cm alumina,2 cm anhydrous sodium sulfate, and sebaceous cotton), and 16 PAHs in soil were detected and analyzed by GC/MS. Use ratio method and principal component analysis (PCA) to research the sources of PAHs using benzene and at the same time (a) pyrene toxicity equivalent concentration, risk quality standard method of ecological risk assessment of PAHs in soil on the surface, and reference for our country the soil environment quality standard (GB 15618-2008) and Canadian soil environmental quality standard for cancer risk ass