《金属有机框架(MOFs)的合成和应用》.pptVIP

* * * * * 金属有机框架(MOFs)的合成和应用 Metal Organic Frameworks（MOFs） Team members： Qin Meng Ye Ting Song Yixuan Gai Linlin Mo Jiamei Liu Yongying Zhou Jinling Li Qianru Sun Tian Du Yina CONTENT Synthetic Chemistry of Materials 1 2 3 Introduction Synthesis of MOFs Application of MOFs Introduction 1 Synthetic Chemistry of Materials Introduction more than 20,000 different MOFs Introduction Synthetic Chemistry of Materials Properities: intriguing topologies higher surface area Designable channel and founctionalized framworks Isoreticular Metal– Organic Framework (IRMOF) was fabricated by Yaghi O M, realizing the transition from static microporous materials to the perfect crystaline mesoporous materials. 1989 1995 2002 1999 2004 2005 2010 2006 The topology theory was applied to the coordination compound by Robson R. The coordination compound with 2d structure, firstly named MOFs, was prepared by Yaghi O M. MOF-5 with simple cubic structure was prepared by Yaghi O M. MIL-100 and MIL-101 materials with macroporous molecular sieve structure were synthesised by Férey’s team. MIL-53(X)with a superior performance in gas separation was synthesised by the Férey’s team. Zeolitic Imidazolate Frameworks(ZIFs) with excellent thermal and chemical stability were synthesised by Yaghi O M. The conception of diverse functional Metal-Organic Skeleton materials(MVT-MOFS) was put forward. Introduction Synthetic Chemistry of Materials Synthesis 2 Synthesis of MOFs 3 Traditional Method 2 Layer-by-Layer Method 3 Microwave-assisted Method Second growth Method 4 1 Aqueous solution of metal organic solvent solution of ligand mixed solvent of water and organic TEXT Traditional Method Layering Method J. Choi, G. Gillan Edward. Inorg.Chem. 2005, 44, 7385. Solvothermal Method Microwave assisted method (1) Dipole rotation (2) Collision takes place (2) Local heating energy efficiency MOF-5 Fig