乙酸调控MIL-53(Fe)的形貌演变及其高效选择性氧化H2S性能.pdfVIP

Chinese Journal of Catalysis 42 (2021) 279–287 催化学报 2021年 第42卷 第2期 |   a v a i l a b l e  a t  w w w . s c i e n c e d i r e c t . c o m   j o u r n a l  h o m e p a g e :  w w w . e l s e v i e r . c o m / l o c a t e / c h n j c   Article   Morphology evolution of acetic acid‐modulated MIL‐53(Fe) for efficient selective oxidation of H2S Xiaoxiao Zheng, Sihui Qi, Yanning Cao, Lijuan Shen *, Chaktong Au, Lilong Jiang # National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China   A R T I C L E I N F O A B S T R A C T Article history:   MIL‐53(Fe) was synthesized using a “modulator approach” that utilizes acetic acid (HAc) as an Received 27 March 2020 additive to control the size and morphology of the resulting crystals. We demonstrate that after Accepted 11 May 2020 activation under vaccum at 100 °C, the MIL‐53(Fe) functions well for H2S selective oxidation. The Published 5 February 2021 introduction of acetic acid in the presence of benzene‐1,4‐dicarboxylic acid (H2BDC) would result in a series of MIL‐53(Fe) nanocrystals (denoted as MIL‐53(Fe)‐xH, x stands for the volume