介孔三氧化二铝的制备及吸附性能研究.docVIP

毕业论文 介孔三氧化二铝的制备及吸附性能研究 姓名 系（部）环境工程与化学系 专业环境工程 指导教师 介孔三氧化二铝的制备及吸附性能研究 摘要 印染废水色度高、组成复杂、有机物禽量高，是较难处理的工业废水Z—， 而对废水屮染料的脱色是印染废水处理过程屮首先需要解决的关键问题。吸附法 因其操作简单、方便有效等特点，被广泛的应用到印染废水的脱色处理屮。 本文采用以PEG (2 000)为模板，A1(NO3)3 - 9H2O为原料，CO(NH2)2为沉 淀剂，在水热条件下的方法合成AI2O3介孔纤维，研究AI2O3介孔纤维对亚甲基蓝 的吸附特性，包括吸附动力学和吸附等温线。 介孔AI2O3对亚甲基蓝的吸附等温式符合Freundlich等温式，不遵循Langmuir 单分子层等温吸附方程，遵循BET多分子层吸附等温方程，故吸附为多分子层吸 附。在吸附动力学的五种模型屮，AI2O3对亚甲基蓝的吸附符合准二级吸附动力 学方程，相关系数R?大于0.99o 关键词：介孔，三氧化二铝，制备，水热法，亚甲基蓝染料，吸附 Preparation and adsorption properties of activated alumina ABSTRACT Printing and dyeing wastewater with high, complex composition, high organic content, is one of the industrial wastewater is difficult to be treated, and the decolorization of dye wastewater is a key issue and must be solved in the process of printing and dyeing wastewater treatment. Adsorption method because of its simple operation, convenient and effective, is widely applied to the decolorization of dyeing wastewater. This paper uses PEG (2000) as template, Al (NO3) 3 ? 9H2O as raw materials, CO (NH2) 2 as precipitant, under hydrothermal conditions of synthesis of AI2O3 mesoporous fiber, AI2O3 mesoporous fiber on the adsorption characteristics including adsorption kinetics and adsorption isotherm. AL2O3 on the isothermal adsorption of methylene blue in accordance with Freundlich isotherm, do not follow the Langmuir monolayer adsorption isotherm equation, follow the BET multi molecular layer adsorption isotherm equation, the adsorption of multimolecular layer adsorption. In the five model the adsorption kinetics of AI2O3 on the adsorption of methylene blue, with the two stage adsorption kinetic equation, correlation coefficient R2 is greater than 0.99. Keywords: mesoporous, AI2O3, oxidation, hydrothermal synthesis, methylene blue, adsorbention 目录 TOC \o 1-5 \h \z 1 / ■ —?— 刖 吞 HYPERLINK \h \z n n n 时难以吸附。k值可视为C为单位浓度时的吸附量，一般说来，k随温度的 升高而降低。 朗格缪尔(Langmuir)等温式： qebC . r . 1 1 1 1 汁 C 1 C q = 或 (1 ) — = 1 或 (2) — = 1 3-2 1 + bC q qeb C qe q qeb qe q