有机半导体和研讨会.pptxVIP

OUTLINE;Molecular Conducting Crystals ;Peierls Transition ;Impurity Pinning;“ Fukuyama - Lee - Rice ” (1987.9.4);Theory of Friction;Molecular Conducting Crystals ;A2B Charge Transfer (CT) Salts : A+1/2 B-1 Cf. A1-xBx : x-0 Carrier Doping into Band Insulators Si:P, Si:B Perylene:Br;Carrier Doping into Insulators＝ Metallic Conduction;Superconductivity in B-doped Diamonds  and even in Silicon !; Typical Molecular Conductors A2B;;Tight - binding approximation based on molecular orbitals works quite well! Validity of Extended Huckel Approx. for one-particle band structures 1980~ H.A.Kobayashi, T.Mori, R.Kato,-- = Even to designing !;Systematic Studies on the Electronic Properties of Molecular Solids;A2B materials;;Charge Order in TMTTF2X ‐1‐;Charge Order in TMTTF2X ‐2‐;“Jerome’s phase diagram”;;;ET2X:κ and λ Types; k-(ET)2X ~ 2D triangular lattice;;1H-NMR spectra;;ET2X with no/weak dimerization;;Viscous electron liquid;;“Neutrino” in Solids;New Particles in α-ET2I3; Single Component Molecular Metals A.Kobayashi-Tanaka-H.Kobayashi(2001);Single component mol metal“Molecules behave like alkaline metal ions”;?The observation of dHvA oscillation (510 Tesla ~ 10% of the 1st Brillouin zone);Π-d Crystals - Metals in the sea of π-electrons -;Phthalocyanine, MPc; So far, crystals of molecules. How about non-crystalline materials? Myoglobin DNA Shin-Tarada-Tokushima-Miyajima-Taguchi (ISSP-RIKEN) 　　　;;4 possible electronic states of Fe in Myoglobin;SXES;;ＤＮＡ;Electrical conductivity:wide variation in experimental results;any experiments in condensed matter should pay attention to;“Contact problem”;　　A Possible Origin of Carrier Doping into DNA;　　　　　　Electronic structure of DNA hydrate v.s. anhydrous Mg;Electronic structure of dry DNA;;;N1s resonant XES of nucleobases;SUMMARY;Molecular Conducting Crystals ;A2B Charge Transfer (CT) Salts : A+1/2 B-1 Cf. A1-xBx