大学化学科学出版社习题解答.docx

工科祀辔哎怨对晶篠程 第1章习题 主讲人: 「IN Is; qol X ZS9X6I X SIQO6E I ZZ?Z6 H (ysroo6z)ossJL $ (ysloo6z)庶?VH (ysIQO6E)3qv 「y ?HOUI ?r ZS9.86I H SPZ6IX Z -守 89?0EI X E + os?s XI H (y SI? 86Z)OSS 二 OUI.N ZZ?Z6 H m?9〒) XZ?OXE + OXI u (ysloo6z)oSH HOUI?N6?ZEH(sp9r)xz?0XE + 0XIH(ysIQ?6z)o￡qv(I) 寸OO9.0H 0s?I6I SPZ6I (IMNOUI?r)、(ysIQO6z)oss 0 0 口?9寸?(二 OUI?N )ysIo?6z)osHJV 0 0 (二 OUI?N )、2siqo6z)osqv 0)zh E + )ZN H 奁)mHN Z --B P33 P33习题1? PAGE # : 2 NH3 (g) N2(g) + 3 H2(g) ArGem(T K) = ArHem(298.15K) - TArSem(298.15K) 1OOO 1000 3( 1OOO 1000 3 ( )?( ) o= 100 100 _ (1°°°)2 100 = 100 (2) ArGm(573.15 K) = ArGeni(573.15K) + RTlnQ =92.22 一 573.15 X19652 X 10 3 + 8.314 X 573.15 X 10 3 In 100 =0.30 kJ-mol1 解： 2 Ag2O (s)= =4Ag(s) + o2(g) AfHem(298.15K)/( kJ-mol1) -30.05 0 0 S°m(298.15K)/(J-mol1 ? K1) 121.3 42.55 205.138 ArH°m(298.15K) = 4X0 + 1X 0-2 X (-30.05) = 60.1 kJ-mol1 ArSem(2915K) = 4X42.55 + 1X205.138 - 2X 121.3 = 132.738 J-mol1-K1 ArGem(298.15K) = ArHem(298.15K) ■ TArSem(298.15K) = 60.1-298.15 X 132.738 X 10 3 =20.52 kJ-mol1 - A0：(298?15K) -20.52 lg A = = 2.303RT 2.303x8.314x 298.15x IO-3 Ke =空糾=理? = 2.5 xlO-4 p° 100 p(O2) = 2.5 x 10~2 kPa P33 P33 习题 1?7 : I ArGem(498.15K) = ArHem(298.15K) - TArSeni(298.15K) = 60.1-498.15 X 132.738 X 10 3 =-6.02 kJ-mol*1 —软4915K) ^02 2.303RT - 2.303x8.314x498.15xl0~3 Ko Ko =卩（。2）P（Q） / 100 =4-28 ArGem(TK) = ArHem(298.15K) - TArSem(298.15K) =60.1 -T X 132.738 X 103 = 0 T = 453K P33习题1?7 : ArGm(T K) = ArGem(TK) + RTlnQ =60.1 一 T X 132.738 X 10 3 + 8.314 X T X 10 3 In 101.325 X 20.95 %/100 0 T 413K P34习题1?8 : 解： n2 (g) + o2(g)= 2NO(g) AfHem(298.15K)/( kJ-mol1) 0 0 90.25 Sem(298?15K)/( J? mol? K) 191.50 205.138 210.761 ArHem(2915K) = 2 X 90.25 -1 XO-1 X0 = 180.5 kJ-mol1 ArSem(2915K) = 2X210.761 X 191.50 -1 X205.138= 24.884 J-mol1-K1 ArGeln(1573.15K) = ArHem(2915K)? TArSem(2915K) = 180.5-1573.15 X 24.884 X 10 3 = 141.35 kJ-mol1 —語(1573.15K) —141.35 2.303RT ~ 2.3O3x8.314xl573.15xlO~3 K6 =2.0x10」 P34习题1?9 : 解：反应 2NO(g) + Cl2(g) = 2NOCl(g)是元反应 (1