松香基二元磁性聚合物微球的制备及表征.docVIP

松香基二元磁性聚合物微球的制备及表征 摘 要 松香是一种宝贵的可再生资源，既可以代替石化资源，减少不可再生资源的使用，又能提高松香的附加值，发挥资源的优势，促进林化产品的充分利用。本文以丙烯酸松香-HEMA酯化物(RAH)、苯乙烯(St)为反应单体，明胶作为分散剂，AIBN作为引发剂，在油酸改性Fe3O4存在下，利用悬浮聚合法制备松香基磁性聚合物微球。探讨了Fe3O4用量、分散剂用量、反应温度、引发剂用量对微球性能的影响，采用FT-IR、TGA、XRD、VSM等对所得微球进行表征，并用标准筛和光学显微镜对微球粒径及形态进行分析。结果表明：成功制备了松香基二元磁性聚合物微球，磁性聚合物微球具有半晶型的结构。在m(RAH) : m(St) = 1 : 2，Fe3O4用量为8 wt.%，明胶用量为6 wt.%，AIBN用量为1 wt.%，85 ℃下反应3 h，90 ℃下熟化2 h，制备的微球球形好，表面光滑，分散均匀，微球具有超顺磁性。 关键词：油酸改性Fe3O4；松香基酯化物；苯乙烯；悬浮聚合法；磁性聚合物微球 Preparation and Characterization of rosin-based binary Magnetic Polymer Microspheres Writer： Teacher： Abstract：Rosin is a kind of valuable renewable resources, which not only can replace fossil resources, reduce the use of non-renewable resources, but also improve the additional value of rosin, play the advantages of resources, and promote the full utilization of forest products. In this study, using acrylic rosin-HEMA(RAH) and Styrene(St) as monomer, gelatin as dispersant, AIBN as initiator,oleic acid modified Fe3O4 as magnetic material, to preparare rosin-based binary magnetic polymer microspheres by suspension polymerization. Exploring the dosage of oleic acid modified Fe3O4、gelatin、AIBN and reaction temperature on the influence of the performance of the particles, respectively. The structures and properties of magnetic polymer microspheres were analyzed and characterized by fourier transform infrared spectroscopy(FT-IR), thermal gravimetric analysis(TGA), X-ray diffraction(XRD), VSM, standard sieve and optical microscopy ,respectively. The results indicated that with the monomer ratio m(RAH) : m(St) = 1 : 2, the dosage of oleic acid modified Fe3O4、AIBN and gelatin was 8 wt.%、1 wt.% and 6 wt.% of the total monomer, respectively, reacting 3 h under 85 ℃, then ripening 2 h under 90 ℃. Finally obtained the rosin-based magnetic polymer microsphere successfully, which shows spherical, crystal strusture, superparamagnetic, and strong magnetic. Key Words：Oleic acid modified Fe3O4；Rosin ester；styrene；S