溶胶-凝胶法制备介孔TiO2及孔径可控研究论文.docVIP

PAGE PAGE IV PAGE I PAGE I 题目：溶胶-凝胶法制备介孔TiO2 及孔径可控研究 溶胶-凝胶法制备介孔二氧化钛及孔径可控的研究 摘 要 介孔TiO2具有大的比表面积、规整孔道结构、极强的吸附性能等特点，在太阳能电池、光催化降解、光催化制氢等领域有很好的应用潜力，同时TiO2无毒、廉价，具有高的化学稳定性，因而受到研究者的广泛关注。 本文以钛酸丁酯为钛源，以聚乙二醇（PEG）为复合模板剂。利用钛酸丁酯水解物与复合模板剂之间的无机-有机自组装反应，实现快速溶胶-凝胶化，将实验周期从通常的数天缩短到几个小时。同时，获得的TiO2凝胶前驱体在空气气氛中煅烧后得到具有介孔结构的纯TiO2光催化材料。利用FT-IR、XRD、ZETA等技术对所制材料进行了系统的表征和分析。 结果表明，制得的所有样品均为锐钛矿相，具有典型的介孔结构。但是对孔径的影响不是很明显。 关键词：快速溶胶凝胶法；介孔TiO2；光催化活性；孔径调节 Synthesis of size-Controlled Mesoporous Titania Particles and Research via a Sol-Gel Method Abstract Mesoporous titanium dioxide (TiO2 ) is widely investigated because of its large surface area, uniform pore structure, and excellent absorption capacity, which make it functional in a wide range of areas such as dye-sensitized solar cells, degradation of pollutant in water and air, and hydrogen evolution. TiO2 also has some other advantages, such as non-toxiciry, low cost and chemical stability. In this paper, butyl titanate as he titanium source, Polyethylene glycol ( PEG) is a composite template . Butyl titanate hydrolyzate and Composite template via a Inorganic - organic self-assembly reaction, so Sol- Gel of the experimental period is generally from several days to several hours. Meanwhile, TiO2 gel precursor obtained after calcination in air to give the pure TiO2 photocatalytic materials with mesoporous structure. The use of FT-IR, XRD, ZETA technology materials were prepared for the characterization and analysis system. The results showed that all the samples are obtained anatase, with a typical mesoporous structure. But the effect on the pore size is not very obvious. Key words: Fast sol-gel; Mesoporous TiO2; Photocatalytic activity; tuning of pore size 目 录TOC \o 1-3 \h \u 11792 1绪论 1 21326 1.1 二氧化钛(TiO2)研究现状 1 27830 1.1.1晶型 1 12041 1.1.2结晶度 2 32414 1.1.3比表面积 2 17826 1.1.4粒径 2 8961 1.2介孔二氧化钛的合成方法 2 14478 1.2.1水热法 3 24601 1.2.2模板法 3 7509 1.2.3溶胶凝胶法 5 17589 1