《结构化学》教学大纲（英文版）.docVIP

PAGE PAGE 7 ‘Structural Chemistry ’Course Syllabus Course CodeCourse Category：Major Basic Majors：Chemistry Semester：Spring Total Hours：54 Hours Credit：3 Lecture Hours：54 Hours Textbooks：《Structural Chemistry》孙墨珑编著，东北林业大学出版社。?? Introduction to Structural Chemistry The major targets this course includes the followings: (1) to introduce the material structure of the basic concepts, basic theory, and basic methods for learning “Structural Chemistry”; (2) to explore the relationship between the microstructures and properties of atoms, molecules, and crystals; (3) to systematically clarify the essence of the periodic law of elements; (4) to deeply and qualitatively clarify the essence of the chemical bonds. This course introduces the basic principles of quantum mechanics and their applications in simple systems, structure of atoms, molecules, and crystals, symmetry of molecular orbitals, molecular orbital theory, and ligand field theory, etc. After learning this course, the students should be able to analyze and solve the basic chemistry problems from the point of view of quantum mechanics. Table of contents Section I (Chapter 1) Basic knowledge of quantum mechanics 1.1 Failures of classical mechanics Black-body radiation Planck’s solution; Photoelectric effect Einstein’s theory; Hydrogen spectrum Bohr’s model. Characteristics of the motion of microscopic particles Wave-particle duality; Uncertainty principle. The basic postulates of quantum mechanics Postulate 1: wavefunction; Postulate 2: Hermitian operators; Postulate 3: Schr?dinger equation; Postulate 4: linearity and superposition; Postulate 5: Pauli exclusion principle. Applications of quantum mechanics in simple cases Free particle in one-dimensional (1D) box; Applications of the 1D-box model in simple chemical systems; Free particle in two-dimensional (2D) three-dimensional (3D) box; Tunneling scanning tunneling microscopy (STM). Section II (Chapter 2) Structures