几篇电解液新型添加剂文献总结.ppt

整理课件 Tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphate 三（六氟异丙基）磷酸酯 CAS：66489-68-7 5V级高电压电解液添加剂，添加量为1wt% 与MCMB具有良好的相容性，与PC共用可防止PC的共嵌分解 Electrolyte Additive in Support of 5 V Li Ion Chemistr——徐康 Journal of The Electrochemical Society,158（3）A337-A342（2011） Phosphate and phosphazene electrolyte additives for Li-ion batteries Meet. Abstr.2012, Volume MA2012-01, Issue 6, Pages 334. Tris(hexafluoro-isopropyl)phosphate was first observed to extend the cycling life of a full 4.7V Li-ion cell using a LiNi0.5Mn1.5O4cathode and a commercial graphite anode. This particular heavily fluorinated phosphate was also usedsuccessfully to allow extended (500 cycles) useful cycling of a 4.8V LiCoPO4cathode vs. lithium 4-(perfluorohexyl)-1,3-dioxolan-2-one 3,3,3-Trifluoropropylene carbonate 三氟代碳酸丙烯酯 CAS：167951-80-6 4-(perfluorobutyl)-1,3-dioxolan-2-one 4-(perfluorooctyl)-1,3-dioxolan-2-one PFO-EC Perfluoroalkyl-substituted ethylene carbonates: Novel electrolyte additives for high-voltage lithium-ion batteries Journal of Power Sources 246 (2014) 184-191 4-全氟辛基碳酸乙烯酯（PFO-EC），正极4.3V氧化分解成膜，降低正极cycles阻抗；负极与EC分解产物聚合形成溶解性小的SEI膜。 PFO-EC在(EC:EMC=3:7，1.2MLiPF6）溶解性较差，最大浓度为2wt%,而其他溶解度为5wt%。推测PFO-EC的分解产物在电解液中的溶解性较低，从而成膜稳定性高。 (EC:EMC=3:7，1.2M LiPF6，0.5wtPFO-EC,Li1.2Ni0.15Mn0.55Co0.1O2-石墨（2.2-4.1,3cycles；C/3 2.2- 4.6 200cycles）容量保持率为66%（172mAh/g）。 Trimethyl phosphite 亚磷酸三甲酯 CAS： 121-45-9 适用于富锂高电压正极，可正极成膜，提高正极材料的电化学性能和热稳定性； 含量不宜超过2wt%。 Trimethyl phosphite as an electrolyte additive for high-voltage lithium-ion batteries using lithium-rich layered oxide cathode Journal of Power Sources 240 (2013) 471-475 Li1.2Mn0.54Ni0.13Co0.13O2：2.5-4.8V，0.1C首次充电；2.5-4.6V，0.5C 100cycles,189.5mAh/g(81.3%)；150mAh/g(5C)、90mAh/g(10C) Tris(pentafluorophenyl)phosphine三(五氟苯基)膦 CAS： 1259-35-4 高电压添加剂，cycles Ok，倍率不佳； 用量为0.5wt%较宜，1wt%性能不佳。 Tris (pentafluorophenyl) phosphine: An electrolyte additive for high voltage Li-ion batteries Electrochemistry Communications 18 (2012) 123–126 Li/LiNi0.5Mn1.5O4,（1M LiPF6，EC：DMC：DEC=1:1:1，0.5wt