生物质炭对铅锌复合污染土壤修复机理的研究.docxVIP

PAGE PAGE 1 生物质炭对铅锌复合污染土壤修复机理的研究 生物质炭对铅锌复合污染土壤修复机理的讨论2945〔2021〕08-0032-04Abstract： In order to study the mechanism of remediation of lead-zinc contaminated soil by material carbon， pine stick carbon， corn straw carbon， straw block carbon， peanut shell carbon， wood granular carbon and mechanism stick carbon were used as heavy metal passivators， and lead-zinc compound polluted soil was taken as the object. Pot experiments were conducted to study the effects of biomass charcoal made from different raw materials on the contents of pH， organic matter， lead and zinc in heavy metal contaminated soil. The results showed that the application of biomass carbon could significantly increase the pH value and organic matter content of heavy metal contaminated soil， and the application of corn straw carbon had the best effect. the contents of lead and zinc in the aboveground part of Brassica chinensis L. were significantly decreased by 65.3% and 41.6% compared with the control. It can be seen that biomass carbon is a kind of heavy metal passivation material which can effectively reduce the content of heavy metals in crops and reduce the toxicity of heavy metals to crops.Keywords： lead-zinc combined pollution; biomass carbon; Brassica chinensis L.我国将来经济进展仍将保持较高的增长速度，随着工业化、城镇化的加快推动，我国土壤重金属污染形势将更加严峻[1]。常见的重金属污染治理技术有物理修复、化学修复和植物修复[2]。其中植物修复技术本钱低、对环境影响小、能使地表稳定、可在去除土壤污染的同时去除污染土壤四周的大气和水体中的污染物，从而有改善生态环境[3]，但是植物修复技术修复的时间长，修复效率低[4]。生物质炭具有巨大的比外表积、丰富的外表官能团、大量的外表负电荷以及高电荷密度的特性，可以通过转变土壤的物理、化学和微生物学性质来实现改进土壤性能，增加土壤肥力的作用[5]。由于生物质炭的这种特性，所以对重金属离子〔Pb2+、Zn2+、Cd2+等〕有着很好的吸附固定作用，且去除率较高[6]，可以使得土壤中重金属的有效态削减，从而降低植物体内的重金属含量。1 材料与方法1.1 供试材料供試土壤采自上虞东关街道小担山铅锌矿区附近苗圃〔120°46′35″E;30°0′4″N〕 0～20cm土层的重金属污染土壤，风干过5mm筛，土壤基本理化性质如下：pH为5.91，有机质2.33mg·kg-1，碱解氮108.5mg·kg-1，有效磷2.63mg·kg-1，速效钾7.4mg·kg-1，全铅325.56mg·kg-1，全锌189.96mg·kg-1。供试植株为小白菜Brassica chinensis L.‘上海青’。供试的生物质炭为松木棒炭、玉米秸秆炭、秸秆块炭、花生壳炭、木质颗粒炭、机制木棒炭六种，由辽宁恒辉新能源科技有限公司在800℃的高温电炉中限氧热裂解制成。其基本理化性质如表1。1.2 试验设计选取长势一致的小白菜‘上海青’作为试验材料，试验于2021年10月17日-2021年12月5日，