排版后科讯成果修改7.pdfVIP

科讯成果 1.Synthesis and Structure of a HgCl2 Coordination Polymer with 1,4-Bis(benzimidazole-1-yl- methylene)benzene (bbmb) HgCl 与1,4-二（苯并咪唑基1-亚甲基）苯（bbmb）生成配位聚合物的 与结构 2 陈雨晴，陈春光，陈红，曹亭，岳忠诚，刘修存，牛云垠* Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry （2013 ）, DOI:10.10802012.758152 In this paper, solution reaction of mercury dichloride with organic multifunctional ligand 1,4-bis(benzimidazole-1-yl- methylene)benzene generated a 1D polymer [HgCl (bbmb)·2H O·CH OH] 1, and the crystal structure has been determined 2 2 3 n (C H Cl Hg N O ), Mr =1428.00, a = 14.703(15) Å, b = 17.248(17) Å, c = 14.91(2) Å, β =114.869(10)°, space group C2/c, 46 60 4 2 8 10 Z = 2, and V = 3430(7) Å3. In 1 the tetrahedral coordination of Hg(II) and the conformation of the bbmb ligand make it a wave-shaped structure. *陈雨晴，2010 级1 班本科生，学号20102310105，在本 中为第一作者 2. Crystal Structure, and Characterization of a Cluster Compound [(BPE)3(WOS3Cu3Br4)2] 簇合物[(BPE)3(WOS3Cu3Br4)2]的晶体结构和特征描述 曹亭，陈红，陈春光，陈雨晴，张振华，牛云垠* Synth. React. Inorg., Metal-Org.Nano-Metal Chem. 2013, 43:4, 417-419 Orange-yellow crystals of the title compound were obtained from the reaction of [NH4]2[WO2S2], CuI, and bpe ·Br2 (1:3:2) in DMF solution. And the crystal system is trigonal, space groupP –3c1, with unit cell parameters a =13.9730(15) Å, b=13.9730 Å, c=18.1365(19) Å, and Z=2. This cluster compound possesses a wheel-shaped supramolecular structure containing tetranuclear cluster core. * 曹亭，2010 级本硕班本科生，学号20102310102，在本 中为第一作者。 3.Syntheses, structures and characterization of three new complexes constructed from triazolyl N- h