DSSC染料敏化太阳能电池-英文课件.pptxVIP

Dye Sensitized Nanocrystalline Photovoltaic CellGroup 1 – Luke, Matt, and JeffTheorySchematic of Graetzel CellTheoryThe adsorbed dye molecule absorbs a photon forming an excited state. [dye*]The excited state of the dye can be thought of as an electron-hole pair (exciton).The excited dye transfers an electron to the semiconducting TiO2 (electron injection). This separates the electron-hole pair leaving the hole on the dye. [dye*+]The hole is filled by an electron from an iodide ion. [2dye*+ + 3I-? 2dye + I3-]Theory: Charge SeparationCharge must be rapidly separated to prevent back reaction.Dye sensitized solar cell, the excited dye transfers an electron to the TiO2 and a hole to the electrolyte.In the PN junction in Si solar cell has a built-in electric field that tears apart the electron-hole pair formed when a photon is absorbed in the junction.ObjectiveLearn about the photovoltaic effect.Understand the Scherrer formula.Procedure: TiO2 SuspensionBegin with 6g colloidal Degussa P25 TiO2Incrementaly add 1mL nitric or acetic acid solution (pH 3-4) nine times, while grinding in mortar and pestleAdd the 1mL addition of dilute acid solution only after previous mixing creates a uniform, lump-free pasteProcess takes about 30min and should be done in ventilated hoodLet equilibrate at room temperature for 15 minutesProcedure: Deposition of TiO2 FilmAlign two conductive glass plates, placing one upside down while the one to be coated is right side upTape 1 mm wide strip along edges of both platesTape 4-5 mm strip along top of plate to be coatedUniformly apply TiO2 suspension to edge of plate5 microliters per square centimeterDistribute TiO2 over plate surface with stirring rodDry covered plate for 1 minute in covered petri dishProcedure: Deposition of TiO2 FilmAnneal TiO2 film on conductive glassTube furnace at 450 oC30 minutesAllow conductive glass to cool to room temperature; will take overnightStore plate for later useProcedure: Preparing Anthrocyanin DyeNatural dye o