离子液体基锂锂离子电解质.docx

PAGE 2 离子液体基锂/锂离子电解质 摘要 　　由于能源短缺和环境污染问题，许多国家已经开始呼吁人们要进行低碳、低排放、节能生活，科研人员也将更多目光投向新能源和新储能技术开发。在人们日常生活中出现一个新现象，那就是新能源电动车逐渐登上世界舞台，并在人们日常生活中的地位越来越重要。目前新能源电动车电池运用最广泛的是锂离子电池，而且它们的商业化程度也较高。但锂离子电池的安全性、充放电性能、比容量等多方面都面临“还需要进一步突破发展”的困境，而影响这些电池性能要求的因素既包含电极材料也包含电解质。电解质是电池中传导离子的载体，在电池工作中起正负两极之间输送、传导电流的桥梁作用。本论文选择以离子液体电解质为本次研究方向。作为电解质，离子液体能够很好地提高锂离子电池在高功率密度条件下工作时的安全性能，极大降低了锂离子电池工作时出现安全隐患事故的概率。本文以离子液体作为研究对象，主要研究合成吡咯烷离子液体的方法并合成吡咯烷离子液体以及对其进行表征，最后对将其作为电解液的LiFePO4/Li电池的电化学性能进行研究。具体实验是用两步法合成具有醚基功能的离子液体-PYR1(2o2)TFSI，配制离子液体电解液PYR1(2o2)TFSI-LiTFSI，组装锂离子电池，然后对合成的吡咯烷离子液体进行表征，对组装好的电池进行电化学性能测试，并对数据进行处理和分析。关键词：锂离子电池，两步法，离子液体，吡咯烷类，醚基离子液体电解液 Abstract 　　 Because of the deficit of energy and the pollution of environment, many countries have begun to call on people to live a low-carbon, low-emission and energy-saving life, and researcher workers will also show more solicitude to the evolvement of new energy and new energy storage technology. A new phenomenon appears in Peoples Daily life, that is, new energy electric vehicles gradually boarded the world stage, and in Peoples Daily life status is more and more important. At present, Lithium-ion battery is the most widely used battery with high commercialization degree in new energy electric vehicle. However, the safety, charge-discharge performance, specific capacity and other aspects of lithium-ion batteries are faced with the dilemma of further breakthrough and development, and the factors affecting the performance requirements of these batteries include both electrode materials and electrolyte. Electrolyte not only acts as the carrier of ion conduction in the battery, but also acts as the bridge between the positive and negative poles of the battery, transferring ions and conducting current in the battery. Ionic liquid electrolyte is chosen as the research direction in this thesis. As an electrolyte, ionic liquid can enhance the security of lithium-ion batteries in the condition of high power density, and greatly reduce the probability of poten