半导体光催化基础第五章-半导体光催化应用.pptxVIP

半导体光催化的应用第1页，共45页。光催化分解水研究；染料敏化太阳能电池；环境保护等领域的研究。第2页，共45页。Hydrogen Economy Based on Solar EnergyPhotosynthesisO2PhotocatalysisH2H2Water INO2PhotovoltaicsFuel CellHydrogen StorageElectrolysisWater OUT第3页，共45页。Photocatalytic Water SplittingCat 1at Cat 1: H+ + e-? H. 2H. ? H2 (2e’s)2H+CB-at Cat 2: M-OH- + h+ ? M -O- + H+ 2M-O- + H2O ? M-OOH + M-OH- 2M-OOH? 2M-OH- + O2 (4e’s)H2hvCat 2H2O ? H2 + 1/2O2 (Overall Water Splitting)VB+photocat*O+ H2OO2 + 2H+2OH-H2 + 1/2O2hv×photocat+ H2O第4页，共45页。H2OO2Photocatalytic Water SplittingEhvPtH+H2e-CBVBh+RuO2Schematic Water oxidation and reduction process over photocatalyst第5页，共45页。Photocatalytic Water SplittingLight Source: UV light or Visible LightOverall water decomposition to H2 and O2Formation H2 or O2 separately (semi-reaction)Key Step: find new photocatalyst Zhigang Zhou GroupK. Domen Group Can Li GroupA. Kudo Group Inoue Group第6页，共45页。紫外光区光催化分解水催化剂体系Under UV Light Quantum Efficiency NiO / SrTiO3Ni / K4Nb6O17NiO / Ni / K2La2Ti3O10NiO / NaTaO3:La ?1% (300nm) K.Domen, J. Phys. Chem., 198610% (300nm) A. Kudo, J Catal., 1989 ? 30% (300nm) K. Domen et al., J. Phys. Chem. 2002? 52% (270nm)A. Kudo et al., JACS, 2003第7页，共45页。可见光区光催化分解水催化剂H2 evolution from 1.0 wt %Pt- Sm2Ti2S2O5 under visible light irradiation(? 440nm)UV-Vis diffuse reflection spectra for Sm2Ti2O7 and Sm2Ti2S2O5A. Ishikawa et al, J. Am. Chem. Soc., 2002, 124, 13547.第8页，共45页。可见光区光催化分解水催化剂H2 evolution from 1.0 wt %Pt- Sm2Ti2S2O5 under visible light irradiation(? 440nm)UV-Vis diffuse reflection spectra for Sm2Ti2O7 and Sm2Ti2S2O5A. Ishikawa et al, J. Am. Chem. Soc., 2002, 124, 13547.第9页，共45页。H2 evolution from 2.0 wt %Pt- ZnIn2S4 under visible light irradiation(? 420nm)UV-Vis diffuse reflection spectra of ZnIn2S4 and ZnSZhibin Lei and Can Li et al, Chem. Commun., 2003, 2142.. 第10页，共45页。H2O2Photocatalyst ＋WaterNature, 414, 625-627, 2001TaO6InO6l420nmIn0.9Ni0.1TaO4mH2 and O2 / mol m Time / h 第11页，共45页。Doping effect on activity of InTaO4 und