热活化提升Pd_C催化剂甲酸电氧化性能的研究.pdfVIP

摘 要：通过微波辅助多元醇方 以XC-72 碳黑作为基体材料制备了Pd/C 材料，对其进行惰性气氛下热 活化处理，制备了热活化 Pd/C 催化剂，并对不同温度制备的Pd/C 催化剂的电催化甲酸氧化反应的性能进行 了探究。在电化学测试中，热活化后的Pd/C 催化剂的电催化活性和长时间运行稳定性都得到了显著提升。此 外，在对热活化温度优化后，发现当热活化温度达到500℃时，所制备的Pd/C-500℃催化剂的甲酸电氧化活性 和稳定性达到最佳水平。分析认为，催化性能的提升来源于Pd 纳米颗粒的结晶性的提高，以及更强的金属载 体的相互作用。 ： ； 热活化 关键词 DFAFC；甲酸氧化 Pd/C 催化剂； Abstract:The Pd/C material was prepared by microwave-assisted polyol method using XC-72 carbon black as the matrix material, and thermally activated under an inert atmosphere to prepare the thermally activated Pd/C cat alyst. The performance for the electrocatalytic formic acid oxidation reaction of the C catalyst was explored. In the electrochemical test, the electrocatalytic activity and long -term operation stability of the thermally activated Pd/C catalyst have been significantly improved, in addition. The thermal activation temperature was optimized, and it was found that when the thermal activation temperature reached 500益, the electro -oxidation activity and stability of formic acid of the prepared Pd/C-500益 catalyst reached the best level. The analysis believes that the improvement of catalytic performance comes from the improvement of the crystallinity of Pd nanoparticles and stronger metal car rier interaction. Key words: DFAFC; formic acid oxidation; Pd/C catalyst; thermal activation 当前，人类社会赖以生存的化石能源资源储量 [ 2 ] 氧化反应 。尽管Pd 催化剂可以赋予DFAFC 非凡 减少、环境污染日益严重。开发新型能源已被广泛认 的功率密度，但因其高成本和有限的储量阻碍了其 为是解决环境和发展问题的有效途径。直接甲酸燃 大规模商业化应用。因此，在降低Pd 用量的同时提 料电池（DFAFCs ）由于其具有无毒、不可燃和高理论 [ 3 ]