当量比天然气发动机Pd_Rh基三元催化器起燃特性研究.pdfVIP

当量比天然气发动机Pd/Rh基三元催化器 起燃特性研究 摘要:为开发一款天然气发动机高效专用三元催化系统，文章建立一种适用于当量比燃烧天然气发动机的 三元催化器(three-way catalyst,TWC)整体模型，研究贵金属种类、排气温度和组分浓度对CH 、NO和CO起 燃特性的影响 。研究结果表明:Pd基催化器上CH 的起燃温度丁% 。和完全转化温度丁90较低;在Pd基催化器 中添加Rh贵金属能促进NO还原,但抑制CO转化;增加H2O的体积分数能促进CH、NO和CO催化转化， 但不同贵金属催化器上CH 、NO和CO起燃性能受H2O体积分数影响的程度不一样;增加O2的体积分数 可以促进CH 、NO和CO催化转化,O2体积分数过高时,CH』和NO转化被抑制;不同贵金属催化器上NO 和CO起燃性能受O2体积分数的影响从大到小顺序为Pd 、Pd/Rh 、Rh,不同贵金属催化器上CH 起燃性能 受O2体积分数的影响从大到小顺序为Rh 、Pd/Rh 、Pd。 关键词:当量比燃烧*天然气发动机* Pd/Rh基三元催化器(TWC )；起燃性能 Study on ignition characteristics of Pd/Rh TWC in a natural gas engine under stoichiometric conditions Abstract : To develop a high-effi ciency special three way catalyst(TWC) for natural gas engines with stoichio­ metric combustion, a TWC integral model was established, and the effects of precious metal and exhaust tem­ perature and component concentration on the ignition characteristics of CH4, NO and CO were studied. The results showed that the ignition temperature ?0 and complete conversion temperature ?0 of CH4 on Pd cata- lys were lower. AddingRhJ oPd ca alys could promo e NO reduc ion bu inhibi COconversion.Thecon- version efficiency of CH4, NO and CO was improved with the increase of H2O volume fraction. However, the ignition characteristics of CH4, NO and CO on different precious metal catalysts were affected by H2 O volume fraction to different degrees. Within a certain range , the conversion efficiency of CH4 , NO and CO was im­ proved with the increase of Q volume fraction. The conversion of CH4 and NO was inhibited when Q volume fraction was too high. The ignition characteristics of NO and CO on Pd catalyst were most affected by O2 vol­ ume fraction , followed by Pd/Rh and Rh , and the ignition characteristics of CH4 on Rh catalyst is most af­ fected by O2 volume fraction , followed by Pd/Rh and Pd. Key words: stoichiome