煤液化沥青制备超级活性炭及其气体吸附特性.docxVIP

爆液化沥青制备超级活性炭及其气体吸附特性 辛凡文;李克健;舒歌平;王洪学;章序文;杨葛灵 【摘要】 Activated carbons were prepared with coal liquefaction asphaltene as carbon source.After the optimization of the synthesis process,activated carbons with specific surface area more than 3 000 m2/g was successfully obtained.The physical and chemical characteristics of activated carbons from coal liquefaction asphaltene (ACCLA) were also investigated with X-ray diffraction (XRD),scanning electron microscope (SEM) and nitrogen adsorption-desorption methods.The adsorption of H2,CH4 and CO2 on these activated carbons were also tested,the relationship between the texture properties and adsorption capacity was discussed.The asprepared samples show excellent performance and good application prospects in gas adsorption.It is found that the maximum adsorption of H2,CH4 and CO2 is 24.85 mmol/g (77 K,400 kPa),4.62 mmol/g (298 K,400 kPa) and 3.57 mmol/g (298 K,100 kPa),respectively.The relationship between the texture properties and adsorption was also discussed.Under test conditions,it is found that the adsorption of H2 is greatly influenced by the specific surface area of the material,and the pore size has a more significant effect on the adsorption of CH4 and CO2.% 使用 KOH作为活化剂,以煤液化沥青为碳源，制得比表面积在3 000 m2/g以上的活性炭 材料，使用X射线衍射(XRD)、扫描电镜(SEM)、氮气吸附和脱附等方法对炭材料的 物理化学特性进行了表征结果表明:煤液化沥青基活性炭(ACCLA)对H2,CH4和 CO2 的吸附量最高分别为 24.85 mmol/g(77 K,400 kPa),4.62 mmol/g(298 K,400 kPa)和3.57 mmol/g(298 K,100 kPa),发现超级活性炭在气体吸附方面表现 出优异的性能和良好的应用前景;同时，对多孔结构特性与吸附量之间的对应关系进 行了讨论，发现在测试条件下川2在吸附量受材料比表面积大小影响很大，而对于 CH4和CO2孔径尺寸的作用更显著. 【期刊名称】《煤炭转化》 【年(卷)，期】2017(040)002 【总页数】6页(P47-52) 【关键词】煤液化沥青;超级活性炭;KOH活化法;孔隙结构;气体吸附 【作者】辛凡文;李克健;舒歌平;王洪学;章序文;杨葛灵 【作者单位】中国神华煤制油化工有限公司上海研究院，煤炭直接液化国家工程实 验室,201108上海;中国神华煤制油化工有限公司上海研究院，煤炭直接液化国家工 程实验室,201108上海;中国神华煤制油化工有限公司上海研究院，煤炭直接液化国 家工程实验室,201108上海;中国神华煤制油化工有限公司上海研究院，煤炭直接液 化国家工程实验室,201108上海;中国神华煤制油化工有限公司上海研究院,煤炭直 接液化国家工程实验室,201108上海;中国神华煤制油化工有限公司上海研究院，煤 炭直接液化国家工程实验室,201108上海 【正文语种】中文 【中图分类】TQ529;TQ424.1 活性炭具有良好的热稳定性和化学稳定性，多孔结构类型丰富可调，这些特点使得