乙醇木质素改性环氧树脂聚醚胺复合材料研究.pdfVIP

乙醇木质素改性环氧树脂/聚醚胺复合材料研究 摘 要：以N ，N-二甲基甲酰胺（DMF）为溶剂，采用溶液共混和机械搅拌相结合的方法将乙醇木质素（EL）添加 到环氧树脂中，再以聚醚胺固化制备得到环氧复合材料。通过拉伸和冲击性能测试、扫描电镜和示差量热分析 研究了木质素添加量对复合材料力学性能、形貌结构和固化反应的影响。结果表明：木质素在DMF 中具有很 好的溶解性，可以得到均一的木质素/环氧树脂复合体系。木质素的加入对环氧树脂/ 聚醚胺体系固化反应具有 一定的促进作用。与纯环氧树脂体系相比，木质素的质量分数为 1.5%时，复合材料的拉伸强度、断裂伸长率 和冲击强度分别提高了3.1% ，14.7%和 13.5%。 关键词：乙醇木质素；环氧树脂；聚醚胺；拉伸强度；断裂伸长率；冲击强度；固化反应 中图分类号：TQ323.5 文献标识码：A 文章编号：1002 － 7432 （2018）02－0043-05 DOI:10.13650/ki.rgxsz.2018.02.009 Study on the ethanol lignin modified epoxy resin/polyetheramine composites GE Zhi-wei ，ZHANG Yan* ，LI Qian ，LU Wei-miao ，JIN Zhen-fu* ，FANG Qun （College of Engineering, Zhejiang Agriculture Forestry University, Collaborative Innovation Center of Bamboo Resources and Efficient Use,Zhejiang Province,Hangzhou 311300, China） Abstract ：Using N，N-dimethylformamide (DMF) as solvent, the ethanol lignin (EL) was introduced into the epoxy resin system by a combination method of solution blending and mechanical agitation, then the system was cured by polyetheramine and the epoxy composites were prepared. The effect of EL amount on the mechanical properties ，morphology and curing reaction of the composites were studied by the testings of tensile strength and impact strengte, SEM and DSC. The results showed that the EL had good solubility in DMF and homogeneous lignin/epoxy resin composite system was obtained. The addition of lignin had a certain promotion effect on the curing reaction of epoxy resin/polyetheramine system. The tensile strength ，elongation at break and impact strength of the composite with 1.5wt% of EL were increased by 3.1%，14.7% and 13.5%，respectively compared with those of pure epoxy resin system. Key words ：ethanol lignin；epoxy resin；polyetheramine；tensile strength；elongation at break；impact strength；curing reaction 0 引 言 被浪费或污染环境的情