基于侵蚀扩散模型的混凝土硫酸根离子传输模拟.pdfVIP

2023年第5期（总第403期） 混 凝土 理论研究 Number 5 in 2023(Total No.403) Concrete THEORETICALRESEARCH doi:10.3969/j.issn.1002-3550.2023.05.008 基于侵蚀扩散模型的混凝土硫酸根离子传输模拟 甘磊，陈官运，沈振中，张文兵 (河海大学水利水电学院，江苏南京210098) 摘要：探讨盐湖、盐渍土地区混凝土内硫酸根离子（SO ）侵蚀问题,基于Fick第二定律，考虑扩散系数随混凝土孔隙率及曲 折度变化，建立受侵蚀混凝土硫酸根离子侵蚀扩散模型，结合COMSOLMultiphysics软件仿真分析不同溶度SO溶液浸泡条件 下混凝土内SO与铝酸钙类物质（CA ）分布演化规律。结果表明：受侵蚀混凝土内SO分布数值结果与试验值吻合较好；溶液浓 度越高SO扩散速度越快；相同侵蚀时间下SO浓度与侵蚀深度呈负指数关系，CA含量由表及里变化，侵蚀表面CA含量最少； 相同侵蚀深度下SO浓度随侵蚀时间增加呈S型增长趋势，而CA含量则显著减小。 关键词：混凝土；硫酸盐侵蚀；Fick定律；扩散；数值模拟 中图分类号：TU528.01 文献标志码：A 文章编号：1002-3550(2023)05-0039-05 Numerical simulation of sulfate ion transport in concrete based on erosion diffusion model GAN Lei, CHEN Guanyun, SHEN Zhenzhong, ZHANG Wenbing (College of Water Conservancy and Hydropower Engineering, Hohai University , Nanjing 210098, China ) Abstract:In order to study the erosion diffusion process of sulfate ion in concrete,a sulfate ion erosion diffusion model has been proposed on the basis of Ficks second law when the change of diffusion coefficient with the porosity and tortuosity of concrete were considered.Combined with COMSOL Multiphysics software,the distribution and evolution of sulfate ion (SO) and calcium aluminate (CA) in concrete soaked with different solubility of SO solution were presented.The results showed that the numerical results of sulfate ion distribution in eroded concrete are in good agreement with the experimental values.The higher the solution concentration,the faster the diffusion rate of sulfate ionUnder the same erosion time,there is a negative exponential relationship between the concentration of sulfate ion and erosion depth.The content of CA changes from outside to inside,and CA nearby th